메뉴 건너뛰기




Volumn 115, Issue 6, 2011, Pages 986-997

Formation of a hybrid compound composed of a saddle-distorted Tin(IV)-porphyrin and a keggin-type heteropolyoxometalate to undergo intramolecular photoinduced electron transfer

Author keywords

[No Author keywords available]

Indexed keywords

AXIAL LIGAND; BENZONITRILES; DONOR-ACCEPTOR COMPLEX; ELECTROCHEMICAL MEASUREMENTS; ELECTROCHEMICAL METHODS; ELECTRON ACCEPTOR; ELECTRON DONORS; ELECTRON-TRANSFER; ENERGY LEVEL; FEMTOSECONDS; HYBRID COMPOUNDS; INTERSYSTEM CROSSING; KEGGIN-TYPE; MALDI TOF MS; NANOSECOND LASERS; NMR STUDIES; PHENYL GROUP; PHOSPHOTUNGSTATE; PHOTO-INDUCED ELECTRON TRANSFER; PORPHYRIN COMPLEXES; TETRAKIS; VARIABLE TEMPERATURE;

EID: 79951534161     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp109863d     Document Type: Article
Times cited : (34)

References (95)
  • 61
    • 0015917658 scopus 로고
    • Sn(IV)-porphyrins can also act as electron acceptors, see
    • Sn(IV)-porphyrins can also act as electron acceptors, see: Fuhrhop, J.-H.; Kadish, K. M.; Davis, D. G. J. Am. Chem. Soc. 1973, 95, 5140
    • (1973) J. Am. Chem. Soc. , vol.95 , pp. 5140
    • Fuhrhop, J.-H.1    Kadish, K.M.2    Davis, D.G.3
  • 78
    • 79951527258 scopus 로고    scopus 로고
    • The positive Δ S value is normal for the dissociation process because of the increase in the freedom by the dissociation. The positive value of the heat of formation (Δ H) indicates that the energy is required to cleave the metal-OMe bond.
    • The positive Δ S value is normal for the dissociation process because of the increase in the freedom by the dissociation. The positive value of the heat of formation (Δ H) indicates that the energy is required to cleave the metal-OMe bond.
  • 79
    • 79951529722 scopus 로고    scopus 로고
    • - (m / z 3120.5) were observed in the lower mass number region.
    • - (m / z 3120.5) were observed in the lower mass number region.
  • 83
    • 70350593917 scopus 로고    scopus 로고
    • For the steric effect on intersystem crossing, see
    • For the steric effect on intersystem crossing, see: Maeda, D.; Shimakoshi, H.; Abe, M.; Hisaeda, Y. Inorg. Chem. 2009, 48, 9853
    • (2009) Inorg. Chem. , vol.48 , pp. 9853
    • Maeda, D.1    Shimakoshi, H.2    Abe, M.3    Hisaeda, Y.4
  • 84
    • 0035796203 scopus 로고    scopus 로고
    • For heavy atom effects of the heavy metal center in intersystem crossing, see
    • For heavy atom effects of the heavy metal center in intersystem crossing, see: Prodi, A.; Kleverlaan, C. J.; Indelli, M. T.; Scandola, F. Inorg. Chem. 2001, 40, 3498
    • (2001) Inorg. Chem. , vol.40 , pp. 3498
    • Prodi, A.1    Kleverlaan, C.J.2    Indelli, M.T.3    Scandola, F.4
  • 95
    • 79951548319 scopus 로고    scopus 로고
    • The change in the spin state from the triplet to the singlet in the ET state may be faster than the slow electron transfer from T* of 2 to 3 in 4.
    • The change in the spin state from the triplet to the singlet in the ET state may be faster than the slow electron transfer from T* of 2 to 3 in 4.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.