Photophysics of ion clusters formed between [Ru(bpy)3] 2+ and the polyoxotungstate anion [S2W18O 62]4-

Journal of Physical Chemistry A

Volumn 108, Issue 36, 2004, Pages 7399-7405

  Seery, Michael K ^a   Guerin, Liz ^a   Forster, Robert J ^a   Gicquel, Etienne ^a,d   Hultgren, Victoria ^b   Bond, Alan M ^b   Wedd, Anthony G ^c   Keyes, Tia E ^a  

^a DUBLIN CITY UNIVERSITY   (Ireland)

^b MONASH UNIVERSITY   (Australia)

^c UNIVERSITY OF MELBOURNE   (Australia)

^d UNIVERSITÉ LIBRE DE BRUXELLES   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CAMERAS; CHARGE COUPLED DEVICES; FOURIER TRANSFORM INFRARED SPECTROSCOPY; OPTICAL RESOLVING POWER; OXIDATION; PHOTOCHEMICAL REACTIONS; PHOTOLYSIS; RAMAN SPECTROSCOPY; REACTION KINETICS;

ELECTRONIC ABSORPTION; ION CLUSTERS; LUMINESCENCE SPECTROSCOPY; MOLECULAR ORBITALS;

ORGANIC COMPOUNDS;

EID: 4544350946     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0482464     Document Type: Article

References (24)

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23. Steady state photolysis studies of the ion clusters showed no evidence for the formation of a stable one-electron-reduced tungstate. This is not surprising, however, as it is likely that fast charge recombination will occur between any electron-transfer product of the ruthenium polypyridyl complex and the tungstate, due to their increased electrostatic association.
24. Seery, M. K.; Fay, N.: McCormac, T.; Dempsey, E.; Keyes, T. E. Photophysics of Ruthenium Polypyridyl Complexes with Phospopolyoxotungstates. Manuscript in preparation.