Phenanthroline-polyoxometalate hybrid compounds and the observation of intramolecular charge transfer

Inorganic Chemistry

Volumn 44, Issue 14, 2005, Pages 4900-4902

  Bar Nahum, Itsik ^a   Narasimhulu, K V ^a   Weiner, Lev ^a   Neumann, Ronny ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 22544480311     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050473c     Document Type: Article

References (27)

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25. 1/2 = 50 mV.
26. One should note that, although phenanthroline may be considered an electron-poor species and a poor candidate for oxidation, in fact its gas-phase ionization potential (IP) is ∼8.3 eV (less than that of toluene and diphenylmethane) http://webbook.nist.gov/chemistry/. The presence of two aminophenyl groups should significantly reduce this IP. Note that the IP of 4-aminobiphenyl is 7.5 eV versus benzene 9.25 eV.
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