Photophysical and Novel Charge-Transfer Properties of Adducts between [RuII(bpy)3]2+ and [S2Mo 18O62]4-

Inorganic Chemistry

Volumn 42, Issue 24, 2003, Pages 7897-7905

  Keyes, Tia E ^a   Gicquel, Etienne ^b   Guerin, Liz ^b   Forster, Robert J ^a   Hultgren, Victoria ^c   Bond, Alan M ^c   Wedd, Anthony G ^d  

^a DUBLIN CITY UNIVERSITY   (Ireland)

^b DUBLIN INSTITUTE OF TECHNOLOGY   (Ireland)

^c MONASH UNIVERSITY   (Australia)

^d UNIVERSITY OF MELBOURNE   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE DERIVATIVE; RUTHENIUM COMPLEX; SULFUR DERIVATIVE;

ARTICLE; CHEMICAL BINDING; CHEMICAL PARAMETERS; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRICITY; ION TRANSPORT; PHOTOLUMINESCENCE; RAMAN SPECTROMETRY; SPECTROSCOPY;

EID: 0345017216     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0206802     Document Type: Article

References (31)

1. Polyoxometalate Chemistry. In Topology via Self-assembly to Applications; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 2001.
2. Papaconstantinou, E. Chem. Soc. Rev. 1989, 18, 1.
3. Neumann, R. Prog. Inorg. Chem. 1998, 47, 317.
4. Bond, A. M.; Way, D. M.; Wedd, A. G.; Compton, R. G.; Booth, J.; Eklund, J. C. Inorg. Chem. 1995, 34, 3378.
5. Kuhn, A.; Anson, F. C. Langmuir 1996, 12, 5481.
6. Hultgren, V. M.; Bond, A. M.; Wedd, A. G. J. Chem. Soc., Dalton Trans. 2001, 1076.
7. Cooper, J. B.; Way, D. M.; Bond, A. M.; Wedd, A. G. Inorg. Chem. 1993, 32, 2416.
8. Ballardini. R.; Gandolfi, M. T.; Balzani, V. Inorg. Chem. 1987, 26, 862.
9. Palmer, R. A.; Piper, T. S. Inorg. Chem. 1966, 5, 864.
10. Diamond, D.; Hanratty, V. Excel for Chemists; John Wiley & Sons, VCH: New York, 1997.
11. Bard, A. J.; Faulkner, L. R. Electrochemical Methods, Fundamentals and Applications, 2nd ed.; J. Wiley and Sons: New York, 2001.
12. Lever, A. B. P. Inorganic Electronic Spectroscopy, 2nd ed.; Elsevier: New York, 1986.
13. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
14. Valeur, B. Molecular Fluorescence, Principles and Applications; Wiley VCH: New York, 2002; pp 72-124.
15. One possibility is that the lifetime of the quenched component based on the 640 nm emission is not represented on this plot because it is too short. However, on the basis of our experimental limitations, this would imply that the rate of quenching exceeds diffusion control. This would then have also to occur by a static or associated complex mechanism.
16. Because of the assumptions inherent in this approach, we estimate the errors in these values to be up to 15%.
17. Ferraro J.; John, R. Introduction to Raman Spectroscopy; Academic Press: New York, 1994.
18. Coates, C. G.; Keyes, T. E.; Hughes, H. P.; Jayaweera, P. M.; McGarvey, J. J.; Vos, J. G. J. Phys. Chem. A 1998, 102, 5013.
19. Dallinger, R. F.; Woodruff, W. H. J. Am. Chem. Soc. 1979, 101, 4391.
20. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; Wiley: New York, 1997; Part B.
21. Fournier, M.; Thouvenot, R.; Rocchiccioli-Deltcheff, C. J. Chem. Soc., Faraday Trans. 1991, 87, 349.
22. See Supporting Information.
23. 2+ dπ to bpy π* transition are not necessarily enhanced here.
24. (a) Fox, M. A.; Cardonna, E.; Gaillard, E. J. Am. Chem. Soc. 1987, 109, 6347.
25. (b) Le Magueres, P.; Hubig, S. M.; Lindeman, S. V.; Veya, P.; Kochi, J. K. J. Am. Chem. Soc. 2000, 122, 10073.
26. (c) Coronado, E.; Galan-Mascaros, J. R.; Gimenez-Saiz, C.; Gomez-Garcia, C. J.; Falvello, L. R.; Delhaes, P. Inorg. Chem. 1998, 37, 2183.
27. Niu, J.-Y.; Wang, J.-P.; Chen, W.; Kennard, C. H. L.; Byriel, K. A. J. Coord. Chem. 2001, 53, 153.
28. Durham, B.; Caspar, J. V.; Nagel, J. K.; Meyer, T. J. J. Am. Chem. Soc. 1982, 104, 4803.
29. 0-0 is the zero-zero spectroscopic energy calculated from the 77 K emission spectrum.
30. Bond, A. M.; Vu, T.; Wedd, A. G. J. Electroanal. Chem. 2000, 494, 96.
31. Vu, T. Ph.D. Thesis, Monash University, Victoria, Australia, 1999.