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[11]), where a zinc silicate is employed as heterogeneous catalyst in flow. In addition, high reaction temperatures are needed in most of the cases reported
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[11]), where a zinc silicate is employed as heterogeneous catalyst in flow. In addition, high reaction temperatures are needed in most of the cases reported.
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34
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33845546747
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together with its strong Lewis acidity makes these complexes suitable candidates for catalysts in additions to C≡C triple bonds. In fact, we have recently reported that the hydration of alkynes can be carried out at room temperature by using these gold complexes as catalysts, see
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Angew. Chem. Int. Ed. 2006, 45, 7896) together with its strong Lewis acidity makes these complexes suitable candidates for catalysts in additions to C≡C triple bonds. In fact, we have recently reported that the hydration of alkynes can be carried out at room temperature by using these gold complexes as catalysts, see
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36
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1a can be purchased from Aldrich as a dimer-toluene aduct
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Mezailles, N.1
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37
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77954777766
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2 was used as solvent since the gold complexes 1a-e can be recovered by precipitation with hexane and the reactants and products are fully soluble
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2 was used as solvent since the gold complexes 1a-e can be recovered by precipitation with hexane and the reactants and products are fully soluble.
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38
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0042703458
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It has been reported that the E-isomer is less prone to isomerise, see: M. M. Baag, A. Kar, N. P. Argade, Tetrahedron 2003, 59, 6489.
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46649107683
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4) as active catalyst for the formation of different ketals and cyclic thioketals from the corresponding alkynes and diols
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4) as active catalyst for the formation of different ketals and cyclic thioketals from the corresponding alkynes and diols.
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34447129755
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Glycerol is a massive by-product of the biodiesel production whose market price has dramatically dropped in the last years, expected to be cheaper than other common diols such as glycol, see: A. Corma, S. Iborra, A. Velty, Chem. Rev. 2007, 107, 2411.
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53849128172
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For intramolecular hydroalkoxylation see: a) Ö. Aksin, N. Krause, Adv. Synth. Catal. 2008, 350, 1106. For others, see:
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