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Carbonyl groups strongly stabilize the singlet state of the nitrene, but as noted previously, this only gets the nitrene singlet state to be near or just barely below the energy of the triplet nitrene
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Thiophene sulfoxide itself cannot be isolated because of self-condensation reactions. However, alkyl substitution of the ring gives sufficient kinetic stabization against the self condensations that they may be handled and isolated. This type of self-condensation of the parent compounds would undoubtedly also plague the sulfilimine and S,C- sulfonium ylides.
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Thiophene sulfoxide itself cannot be isolated because of self-condensation reactions. However, alkyl substitution of the ring gives sufficient kinetic stabization against the self condensations that they may be handled and isolated. This type of self-condensation of the parent compounds would undoubtedly also plague the sulfilimine and S,C- sulfonium ylides.
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