Unexpected four-membered over six-membered ring formation during the synthesis of azaheterocyclic phosphonates: Experimental and theoretical evaluation

Journal of the American Chemical Society

Volumn 128, Issue 26, 2006, Pages 8468-8478

  Van Speybroeck, Veronique ^a   Moonen, Kristof ^a   Hemelsoet, Karen ^a   Stevens, Christian V ^a   Waroquier, Michel ^a  

^a GHENT UNIVERSITY   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; LITHIUM; MOLECULAR STRUCTURE; PHASE TRANSITIONS; SODIUM; SYNTHESIS (CHEMICAL);

DIMETHYL ETHER SOLVENT MOLECULES; INTERMOLECULAR REACTIONS; RING FORMATION; SOLVENT EFFECTS;

AROMATIC COMPOUNDS;

ALLYL COMPOUND; ANION; AZAHETEROCYCLIC PHOSPHONATE DERIVATIVE; BETA LACTAM; CARBON; DIMETHYL ETHER; GAMMA ANION; HETEROCYCLIC COMPOUND; LITHIUM; NITROGEN; PHOSPHONIC ACID DERIVATIVE; PHOSPHORAMIDIC ACID; SODIUM; SOLVENT; UNCLASSIFIED DRUG;

AB INITIO CALCULATION; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CYCLIZATION; MOLECULE; SOLVATION; SYNTHESIS;

AZA COMPOUNDS; CYCLIZATION; MODELS, CHEMICAL; MODELS, MOLECULAR; MOLECULAR STRUCTURE; PHOSPHONIC ACIDS; QUANTUM THEORY; SOLUBILITY; STEREOISOMERISM;

EID: 33745728231     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0584119     Document Type: Article

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