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Volumn 75, Issue 24, 2010, Pages 8410-8415

Mo(CO)6-mediated carbamoylation of aryl halides

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS AMMONIA; ARYL HALIDES; CARBAMOYLATION; MOLYBDENUM COMPLEX; PRIMARY AMIDES; SIMPLE METHOD; SYNTHESIS OF AMIDE; TERTIARY AMIDES; THREE-COMPONENT COUPLING REACTION;

EID: 78650324851     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo101611g     Document Type: Article
Times cited : (101)

References (85)
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    • Just after the submission of our manuscript, Roberts and co-workers reported molybdenum-mediated carbonylation of aryl halides using microwave irradiation. See
    • Just after the submission of our manuscript, Roberts and co-workers reported molybdenum-mediated carbonylation of aryl halides using microwave irradiation. See: Roberts, B.; Liptrot, D.; Alcaraz, L.; Luker, T.; Stocks, M. J. Org. Lett. 2010, 12, 4280
    • (2010) Org. Lett. , vol.12 , pp. 4280
    • Roberts, B.1    Liptrot, D.2    Alcaraz, L.3    Luker, T.4    Stocks, M.J.5
  • 29
    • 0001154012 scopus 로고
    • 2-carbon halogen bond to molybdenum or tungsten carbonyl complexes, see
    • 2-carbon halogen bond to molybdenum or tungsten carbonyl complexes, see: Richmond, T. G.; King, M. A.; Kelson, E. P.; Arif, A. M. Organometallics 1987, 6, 1995
    • (1987) Organometallics , vol.6 , pp. 1995
    • Richmond, T.G.1    King, M.A.2    Kelson, E.P.3    Arif, A.M.4
  • 35
    • 0037112673 scopus 로고    scopus 로고
    • For a review about palladium-catalyzed coupling reactions of aryl chlorides, see
    • For a review about palladium-catalyzed coupling reactions of aryl chlorides, see: Littke, A. F.; Fu, G. C. Angew. Chem., Int. Ed. 2002, 41, 4176
    • (2002) Angew. Chem., Int. Ed. , vol.41 , pp. 4176
    • Littke, A.F.1    Fu, G.C.2
  • 45
    • 78650354779 scopus 로고    scopus 로고
    • For references related to chelation assisted oxidative addition of Ar-X to tungsten or molybdenum carbonyl complexes, see refs 6a, 6b, 6c, and 6e
    • For references related to chelation assisted oxidative addition of Ar-X to tungsten or molybdenum carbonyl complexes, see refs 6a, 6b, 6c, and 6e.
  • 46
    • 23044513118 scopus 로고    scopus 로고
    • For palladium-catalyzed aminocarbonylation reactions by using water as the solvent, see
    • For palladium-catalyzed aminocarbonylation reactions by using water as the solvent, see: Wu, X.; Larhed, M. Org. Lett. 2005, 7, 3327
    • (2005) Org. Lett. , vol.7 , pp. 3327
    • Wu, X.1    Larhed, M.2
  • 49
    • 0032580469 scopus 로고    scopus 로고
    • For Pd-catalyzed primary amides preparation, see
    • For Pd-catalyzed primary amides preparation, see: Morera, E.; Ortar, G. Tetrahedron Lett. 1998, 39, 2835
    • (1998) Tetrahedron Lett. , vol.39 , pp. 2835
    • Morera, E.1    Ortar, G.2
  • 54
    • 78650404096 scopus 로고    scopus 로고
    • 4NCl in the reaction of primary and secondary amine, chloride anion may coordinate to the molybdenum center and stabilize the intermediates. In the reaction with aqueous ammonia, ammonia or water molecule may coordinate and stabilize the molybdenum intermediate instead of chloride anion
    • 4NCl in the reaction of primary and secondary amine, chloride anion may coordinate to the molybdenum center and stabilize the intermediates. In the reaction with aqueous ammonia, ammonia or water molecule may coordinate and stabilize the molybdenum intermediate instead of chloride anion.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.