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Volumn 29, Issue 17, 2010, Pages 3955-3965

Arene-ruthenium(II) complexes containing amino-phosphine ligands as catalysts for nitrile hydration reactions

Author keywords

[No Author keywords available]

Indexed keywords

AMINO GROUP; AQUEOUS MEDIUM; BIFUNCTIONAL CATALYSIS; COCATALYST; DONOR LIGANDS; EFFICIENT CATALYSTS; HYDRATION PROCESS; HYDRATION REACTION; LEWIS ACID; ORGANONITRILES; P-CYMENE; PHOSPHINE LIGANDS; REACTION CONDITIONS; RUTHENIUM COMPLEXES; TRIPHENYL PHOSPHINES;

EID: 77956417733     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om1006227     Document Type: Article
Times cited : (87)

References (122)
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    • pa = 1.81 V) were run under identical experimental conditions.
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    • A two-phase system (water/organic products) is observed, the reaction taking place probably at the interface.
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    • 6-arene)] (14a - d) is not completely homogenous, and consequently, solubility issues cannot be completely discarded to explain the different reactivities observed.
    • 6-arene)] (14a - d) is not completely homogenous, and consequently, solubility issues cannot be completely discarded to explain the different reactivities observed.
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    • pH measurements on 0.016 M aqueous solutions of complexes 11aa - 13db (the same concentration used in the catalytic experiments) confirm this hypothesis. The values obtained, ranging from 7.12 to 7.37, indicate that when dissolved in water 11aa - 13db are able to generate a slightly basic media.
    • pH measurements on 0.016 M aqueous solutions of complexes 11aa - 13db (the same concentration used in the catalytic experiments) confirm this hypothesis. The values obtained, ranging from 7.12 to 7.37, indicate that when dissolved in water 11aa - 13db are able to generate a slightly basic media.
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