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pa = 1.81 V) were run under identical experimental conditions.
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77956409945
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6-coordinated hexamethylbenzene and the tert -butyl substituent on the amino-phosphine ligand.
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6-coordinated hexamethylbenzene and the tert -butyl substituent on the amino-phosphine ligand.
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109
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77956398841
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A two-phase system (water/organic products) is observed, the reaction taking place probably at the interface.
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A two-phase system (water/organic products) is observed, the reaction taking place probably at the interface.
-
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110
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77956415760
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3)] (12cb) (5 mol %) generates benzamide in only 58% and 60% GC yield, respectively, after 24 h of heating at 100 °C (to be compared with entry 14 in Table 2).
-
3)] (12cb) (5 mol %) generates benzamide in only 58% and 60% GC yield, respectively, after 24 h of heating at 100 °C (to be compared with entry 14 in Table 2).
-
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111
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77956407098
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6-arene)] (14a - d) is not completely homogenous, and consequently, solubility issues cannot be completely discarded to explain the different reactivities observed.
-
6-arene)] (14a - d) is not completely homogenous, and consequently, solubility issues cannot be completely discarded to explain the different reactivities observed.
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112
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114
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77956415502
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pH measurements on 0.016 M aqueous solutions of complexes 11aa - 13db (the same concentration used in the catalytic experiments) confirm this hypothesis. The values obtained, ranging from 7.12 to 7.37, indicate that when dissolved in water 11aa - 13db are able to generate a slightly basic media.
-
pH measurements on 0.016 M aqueous solutions of complexes 11aa - 13db (the same concentration used in the catalytic experiments) confirm this hypothesis. The values obtained, ranging from 7.12 to 7.37, indicate that when dissolved in water 11aa - 13db are able to generate a slightly basic media.
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115
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