Luminescent Au(I)/Cu(I) Alkynyl clusters with an ethynyl steroid and related aliphatic ligands: An octanuclear Au4Cu4 cluster and luminescence polymorphism in Au3Cu2 clusters

Journal of the American Chemical Society

Volumn 132, Issue 35, 2010, Pages 12307-12318

  Manbeck, Gerald F ^a   Brennessel, William W ^a   Stockland, Robert A ^b   Eisenberg, Richard ^a  

^a UNIVERSITY OF ROCHESTER   (United States)

^b BUCKNELL UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLIDES; ALIPHATIC LIGANDS; ALKYNYLS; CRYSTALLOGRAPHIC STUDIES; CU COMPLEXES; DFT CALCULATION; ELECTRONIC TRANSITION; EMISSION ENERGIES; ETHISTERONE; ETHYL ACETATES; ETHYNYL; HYDROGEN BONDINGS; HYDROXYL GROUPS; IMINIUM; NMR SPECTROSCOPY; ORBITALS; PENTANUCLEAR CLUSTERS; PENTANUCLEAR COMPLEXES; TRIPHENYL PHOSPHINES;

ESTERS; ETHANOL; HYDROGEN BONDS; LUMINESCENCE; METHANOL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMORPHISM; QUANTUM YIELD; X RAY CRYSTALLOGRAPHY;

GOLD COMPOUNDS;

[[GOLD(ETHISTERONE) 2] 4 COPPER 4]; [BIS(TRIPHENYLPHOSPHINE)IMINIUM][[GOLD(1 ETHYNYL CYCLOHEXANOL) 2] 3 COPPER 2]; [BIS(TRIPHENYLPHOSPHINE)IMINIUM][[GOLD(1 ETHYNYL CYCLOPENTANOL) 2] 3 COPPER 2]; [BIS(TRIPHENYLPHOSPHINE)IMINIUM][[GOLD(ETHISTERONE) 2] 3 COPPER 2]; [BIS(TRIPHENYLPHOSPHINE)IMINIUM][GOLD((1 ETHYNYL CYCLOHEXANO) 2]; [BIS(TRIPHENYLPHOSPHINE)IMINIUM][GOLD(1 ETHYNYL CYCLOPENTANOL) 2]; [BIS(TRIPHENYLPHOSPHINE)IMINIUM][GOLD(ETHISTERONE) 2]; ACETIC ACID DERIVATIVE; ACETIC ACID ETHYL ESTER; ACETYLENE; ALCOHOL; ALIPHATIC COMPOUND; ALKYNE DERIVATIVE; COPPER COMPLEX; CYCLOHEXANOL DERIVATIVE; ETHISTERONE; GOLD COMPLEX; HYDROXYL GROUP; METHANOL; PENTANOL; UNCLASSIFIED DRUG; WATER;

ARTICLE; CHEMICAL STRUCTURE; COLOR; DENSITY FUNCTIONAL THEORY; HYDROGEN BOND; LUMINESCENCE; MOLECULE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM YIELD; SOLID STATE; X RAY CRYSTALLOGRAPHY;

ALKYNES; ALLOYS; COPPER; CRYSTALLOGRAPHY, X-RAY; GOLD; LIGANDS; LUMINESCENCE; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; STEROIDS;

EID: 77956245502     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja103400e     Document Type: Article

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