Ring-construction/stereoselective functionalization cascade: Total synthesis of pachastrissamine (Jaspine B) through palladium-catalyzed bis-cyclization of propargyl chlorides and carbonates

Journal of Organic Chemistry

Volumn 75, Issue 11, 2010, Pages 3831-3842

  Inuki, Shinsuke ^a   Yoshimitsu, Yuji ^a   Oishi, Shinya ^a   Fujii, Nobutaka ^a   Ohno, Hiroaki ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BENZAMIDES; BROMOALLENES; FUNCTIONALIZATIONS; FUNCTIONALIZED; LEAVING GROUPS; MARINE NATURAL PRODUCTS; PACHASTRISSAMINE (JASPINE B); PROPARGYL CHLORIDES; TETRA-HYDROFURAN; TOTAL SYNTHESIS;

AMIDES; CARBONATES; CHLORINE COMPOUNDS; PALLADIUM; SYNTHESIS (CHEMICAL);

CYCLIZATION;

ALLENE DERIVATIVE; BENZAMIDE; BROMOALLENE DERIVATIVE; CARBONIC ACID DERIVATIVE; CHLORIDE; COPPER; HYDROXYL GROUP; NATURAL PRODUCT; NUCLEOPHILE; PACHASTRISSAMINE; PALLADIUM; PROPARGYL CHLORIDE DERIVATIVE; TETRAHYDROFURAN; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CATALYSIS; CHLORINATION; CYCLIZATION; HUMAN; STEREOCHEMISTRY; SYNTHESIS;

ALKYNES; CARBONATES; CATALYSIS; CHLORIDES; CYCLIZATION; PALLADIUM; SPHINGOSINE; STEREOISOMERISM;

EID: 77952967418     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo100544v     Document Type: Article

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