Stereoselective stille coupling of enantiopure haloallenes and alkenylstannanes for the synthesis of allenyl carotenoids. Experimental and computational studies

Journal of Organic Chemistry

Volumn 73, Issue 17, 2008, Pages 6534-6541

  Vaz, Belén ^a   Pereira, Raquel ^a   Pérez, Martín ^a   Álvarez, Rosana ^a   De Lera, Angel R ^a  

^a UNIVERSITY OF VIGO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; PALLADIUM; STEREOSELECTIVITY;

ALKENYLSTANNANES; EN-ROUTE; ENANTIOPURE;

DIMETHYLFORMAMIDE;

3 HYDROXY 3,5,5 TRIMETHYL 4 (IODOVINYLIDENE)CYCLOHEXYLACETATE; 3 HYDROXY 4 (5 HYDROXYPENTA 1,3 DIENYLIDENE) 3,5,5 TRIMETHYLCYCLOHEXYLACETATE; 4 (2 BROMOVINYLIDENE) 3,5,5 TRIMETHYL 3 (TRIMETHYLSILYLOXY)CYCLOHEXYLACETATE; 4 (2 IODOVINYLIDENE) 3,5,5 TRIMETHYL 3 (TRIMETHYLSILYLOXY)CYCLOHEXYLACETATE; 4 (5 HYDROXYPENTA 1,3 DIENYLIDENE) 3,5,5 TRIMETHYL 3 (TRIMETHYLSILYLOXY)CYCLOHEXYLACETATE; 5 (TERT BUTYLDIMETHYLSILYLOXY) 2 (5 HYDROXYPENTA 1,3 DIENYLIDENE) 1,3,3 TRIMETHYLCYCLOHEXANOL; 5 (TERT BUTYLDIMETHYLSILYLOXY) 2 (5 HYDROXYPENTA 1,3 DIENYLIDENE] 1,3,3 TRIMETHYLCYCLOHEXANOL; 6 (2 BROMOVINYLIDENE) 3 (TERT BUTYLDIMETHYLSILYLOXY) 1,5,5 TRIMETHYLCYCLOHEXAN 1 OL; [4 (TERT BUTYLDIMETHYLSILYLOXY) 2,2,6 TRIMETHYL 7 OXABICYCLO[4.1.0]HEPTAN 1YL]PENT 2 EN 4 YN 1 OL; ALLENE DERIVATIVE; CAROTENOID; HALOGEN; PALLADIUM; PALLADIUM COMPLEX; SOLVENT; TIN DERIVATIVE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYST; CHEMICAL BOND; DENSITY FUNCTIONAL THEORY; ENERGY TRANSFER; EXPERIMENTAL STUDY; MATHEMATICAL COMPUTING; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; STILLE REACTION; SYNTHESIS; X RAY DIFFRACTION;

EID: 51549093962     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo800756b     Document Type: Article

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