Quantification of crocetin esters in saffron (Crocus sativus L.) using Raman spectroscopy and chemometrics

Journal of Agricultural and Food Chemistry

Volumn 58, Issue 10, 2010, Pages 6011-6017

  Anastasaki, Eirini G ^a   Kanakis, Charalabos D ^a   Pappas, Christos ^a   Maggi, Luana ^b   Zalacain, Amaya ^b   Carmona, Manuel ^b   Alonso, Gonzalo L ^b   Polissiou, Moschos G ^a  

^a AGRICULTURAL UNIVERSITY OF ATHENS   (Greece)

^b UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

Coloring strength; Crocins; HPLC chromatography; Partial least squares PLS; Raman spectroscopy; Saffron

Indexed keywords

CAROTENOID; CROCETIN; CROCIN; ESTER;

ARTICLE; CALIBRATION; CHEMISTRY; COLOR; CROCUS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; METHODOLOGY; QUALITY CONTROL; RAMAN SPECTROMETRY; REGRESSION ANALYSIS; REPRODUCIBILITY; PROCEDURES;

CALIBRATION; CAROTENOIDS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; COLOR; CROCUS; ESTERS; LEAST-SQUARES ANALYSIS; QUALITY CONTROL; REPRODUCIBILITY OF RESULTS; SPECTRUM ANALYSIS, RAMAN;

CROCUS SATIVUS;

EID: 77952634012     PISSN: 00218561     EISSN: 15205118     Source Type: Journal    
DOI: 10.1021/jf100143n     Document Type: Article

References (29)

1. ISO 3632/TS-1,2 Saffron (Crocus sativus L.) Part 1: Specifications, Part 2: Test Methods; ISO: Geneva, Switzerland, 2003.
2. Tarantilis, P. A.; Polissiou, M.; Manfait, M. Separation of picrocrocin, cis-trans-crocins and safranal of saffron using high-performance liquid chromatography with photodiode-array detection J. Chromatogr., A 1994, 664, 55-61
3. Tarantilis, P. A.; Tsoupras, G.; Polissiou, M. Determination of saffron (Crocus sativus L.) components in crude plant extract using high-performance liquid chromatography- UV-Visible photodiode-array detection-mass spectrometry J. Chromatogr., A 1995, 699, 107-118
4. Sujata, V.; Ravishankar, G. A.; Venkataraman, L. V. Methods for the analysis of the saffron metabolites crocin, crocetins, picrocrocin and safranal for the determination of the quality of the spice using thin-layer chromatography, high-performance liquid chromatography and gas chromatography J. Chromatogr., A 1992, 624, 497-502
5. Lozano, P.; Castellar, M. R.; Siamncas, M. J.; Iborra, J. L. Quantitative high-performance liquid chromatographic method to analyse commercial saffron (Crocus sativus L.) products J. Chromatogr., A 1999, 830, 477-483
6. Carmona, M.; Zalacain, A.; Sanchez, A. M.; Novella, J. L.; Alonso, G. L. Crocetin esters, picrocrocin and its related compounds present in Crocus sativus stigmas and Gardenia jasminoides fruits. Tentative identification of seven new compounds by LC-ESI-MS J. Agric. Food Chem. 2006, 54, 973-979
7. Ozaki, Y.; Cho, R.; Ikegaya, K.; Muraishi, S.; Kawaucji, K. Potential of Near-Infrared Fourier Transform Raman spectroscopy in food analysis Appl. Spectrosc. 1992, 46 (10) 1503-1507
8. Li-Chan, E. C. Y. The application of Raman spectroscopy in food science Trends Food Sci. Technol. 1996, 7, 361-370
9. Archibald, D. D.; Kays, S. E.; Himmelsbach, D. S.; Barton, F. E., II Raman and NIR spectroscopic methods for the determination of total dietary fiber in cereal foods: a comparative study Appl. Spectrosc. 1998, 52 (1) 22-31
10. Muik, B.; Lendl, B.; Molina-Diaz, A.; Ayora-Canada, M. J. Direct, reagent-free determination of free fatty acid content in olive oil and olives by Fourier transform Raman spectroscopy Anal. Chim. Acta 2003, 487, 211-220
11. Mirghami, M. E. S.; Che man, Y. B. A new method for determinhg gossypol in cottonseed oil by FT-IR spectroscopy J. Am. Oil Chem. Soc. 2003, 80, 625-628
12. Wold, J. P.; Marquardt, B. J.; Dable, B. K.; Robb, D.; Hatlen, B. Rapid quantification of carotenoids and fat in atlantic salmon (Salmo salar L.) by Raman spectroscopy and chemometrics Appl. Spectrosc. 2004, 58 (4) 395-403
13. Schulz, H.; Baranska, M. Identification and quantification of valuable plant substances by IR and Raman spectroscopy Vib. Spectrosc. 2007, 43, 13-25
14. Petrakis, E.; Kimbaris, A.; Pappas, C.; Tarantilis, P.; Polissiou, M. Quantitative determination of pennyroyal oil by FT-IR spectroscopy J. Agric. Food Chem. 2009, 57, 10044-10048
15. Zalacain, A.; Ordoudi, S. A.; Diaz-Plata, E. M.; Carmona, M.; Blazquez, I.; Tsimidou, M. Z.; Alonso, G. L. Near-Infrared spectroscopy in saffron quality control: determination of chemical composition and geographical origin J. Agric. Food Chem. 2005, 53, 9337-9341
16. Tarantilis, P. A.; Beljebbar, A.; Manfait, M.; Polissiou, M. FT-IR, FT-Raman spectroscopic study of carotenoids from saffron (Crocus sativus L.) and some derivatives Spectrochim. Acta, Part A 1998, 54, 651-657
17. Assimiadis, M. K.; Tarantilis, P. A.; Polissiou, M. G. UV-Vis, FT-Raman and H-NMR spectroscopies of cis-trans carotenoids from saffron (Crocus sativus L.) Appl. Spectrosc. 1998, 52 (4) 519-522
18. Schulz, H.; Baranska, M; Baranski, R. Potential of NIR-FT-Raman spectroscopy in natural carotenoid analysis Biopolymers 2005, 77, 212-221
19. Sanchez, A. M.; Carmona, M.; Zalacain, A.; Carot, J. M.; Jabaloyes, J. M.; Alonso, G. L. Rapid determination of crocetin esters and picrocrocin from saffron spice (Crocus sativus L.) using UV-Visible spectrophotometry for quality control J. Agric. Food Chem. 2008, 56, 3167-3175
20. Speranza, G.; Dada, G.; Manitto, P.; Monti, D.; Grammatica, P. 13-cis crocin: a new crocinoid of saffron Gazz. Chim. Ital. 1984, 114, 189-192
21. Martens, H.; Naes, T. Assessment, validation and choice of calibration method. In Multivariate calibration; John Wiley & Sons: Chichester, U.K., 1989; Chapter 4, p 237.
22. Malley, D. F.; Yesmin, L.; Wray, D.; Edwards, S. Application of Near-Infrared spectroscopy in analysis of soil mineral nutrients Commun. Soil Sci. Plant Anal. 1999, 30, 999-1012
23. Dunn, B. W.; Beecher, H. G.; Batten, G. D.; Ciavarella, S. The potential of near-infrared reflectance spectroscopy for soil analysis-a case study from the Riverine plain of south-eastern Australia Aust. J. Exp. Agric. 2002, 42, 607-614
24. Du, C.; Zhou, J.; Wang, H.; Chen, X.; Zhu, A.; Zhang, J. Determination of soil properties using Fourier transform mid-infrared photoacoustic spectroscopy Vib. Spectrosc. 2009, 49, 32-37
25. Huang, Y.; Rogers, T. M.; Wenz, M. A.; Cavinato, A. G.; Mayes, D. M.; Bledsoe, G. E.; Rasco, B. A. Detection of sodium chloride in cured salmon roe by SW-NIR spectroscopy J. Agric. Food Chem. 2001, 49, 4161-4167
26. Baranska, H.; Labudzinska, A.; Terpinski, J. Identification of organic compounds. In Laser Raman Spectroscopy Analytical Applications; PWN- Polish scientific publishers: Warsaw, Poland; Mayer, J. R., translation ed.; Wiley: New York, 1987; Chapter 4, p 122.
27. Saito, S.; Tasumi, M. Normal-coordinate analysis of β-carotene isomers and assignments of the Raman infrared bands J. Raman Spectrosc. 1983, 14, 310-321
28. -1) of all-trans and 15-cis isomers of β-carotene in the solid state and in solution. Measurements with various laser lines from ultraviolet to red J. Raman Spectrosc. 1983, 14, 299-309
29. Choquette, S. J.; Etz, E. S.; Hurst, W. S.; Blackburn, D. H.; Leigh, S. D. Relative intensity correction of Raman soectrometers:NIST SRMs 2241 through 2243 for 785 nm, 532 nm, and 488nm/514.5 excitation Appl. Spectrosc. 2007, 61 (2) 117-129