Quantitative determination of pulegone in pennyroyal oil by FT-IR spectroscopy

Journal of Agricultural and Food Chemistry

Volumn 57, Issue 21, 2009, Pages 10044-10048

  Petrakis, Eleftherios A ^a   Kimbaris, Athanasios C ^b   Pappas, Christos S ^a   Tarantilis, Petros A ^a   Polissiou, Moschos G ^a  

^a AGRICULTURAL UNIVERSITY OF ATHENS   (Greece)

^b DEMOCRITUS UNIVERSITY OF THRACE   (Greece)

Author keywords

Essential oil; Fourier transform infrared spectroscopy; Hydrodistillation; Mentha pulegium; PLS; Quantitative analysis

Indexed keywords

CYCLOHEXANONE DERIVATIVE; ESSENTIAL OIL; PENNYROYAL OIL; PULEGONE; TERPENE; VEGETABLE OIL;

ARTICLE; CHEMISTRY; EVALUATION; INFRARED SPECTROSCOPY; MENTHA; METHODOLOGY;

CYCLOHEXANONES; MENTHA; MONOTERPENES; OILS, VOLATILE; PLANT OILS; SPECTROSCOPY, FOURIER TRANSFORM INFRARED;

MENTHA; MENTHA PULEGIUM;

EID: 70449103463     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf9026052     Document Type: Article

References (23)

1. Barceloux, D. G. Pennyroyal and Pulegone (Menthapulegium L.). In Medical Toxicology of Natural Substances: Foods, Fungi, Medicinal Herbs, Plants and Venomous Animals; John Wiley & Sons, Inc.: Hoboken, NJ, 2008; pp 563-567.
2. Karousou, R.; Balta, M.; Hanlidou, E.; Kokkini, S. "Mints", smells and traditional uses in Thessaloniki (Greece) and other Mediterranean countries, J. Ethnopharmacol. 2007, 109, 248-257.
3. Hayes, J. R.; Stavanja, M. S.; Lawrence, B. M. Biological and toxicological properties of mint oils and their major isolates: Safety assessment. In Mint: The Genus Mentha; Lawrence, B. M., Ed.; CRC Press, Taylor & Francis Group: 2007; pp 462-477.
4. Khojasteh-Bakht, S. C.; Chen, W.; Koenigs, L. L.; Peter, R. M.; Nelson, S. D. Metabolism of (R)-(+)-pulegone and (R)-(+)-menthofuran by human liver cytochrome P-450s: Evidence for formation of a furan epoxide, Drug Metab. Dispos. 1999, 27, 574-580.
5. Ravid, U.; Putievsky, E.; Katzir, I. Chiral GC analysis of (1R)(-)pulegone with high, enantiomeric purity in essential oils of some Lamiaceae aromatic plants. Flavour Fragrance J. 1994, 9, 205207.
6. Council Directive 88/388/EEC of 22 June 1988 on the approximation of the laws of the Member States relating to flavorings for use in. foodstuffs and to source materials for their production. Official Journal L 184 (July 15, 1988).
7. European Commission - SCF (Scientific Committee on Food). Opinion, of the Scientific Committee on Food on pulegone and menthofuran. Add 2 final, July 25, 2002.
8. Engel, W. In vivo studies on the metabolism, of the monoterpene pulegone in humans using the metabolism, of ingestion-correlated amounts (MICA) approach: Explanation for the toxicity differences between (S)-(-)- and (R)-(+)-pulegone. J. Agric. Food Chem. 2003, 51, 6589-6597.
9. Kokkini, S.; Hanlidou, E.; Karousou, R. Clinal variation of Mentha pulegium essential oils along the climatic gradient of Greece. J. Eissent. Oil Res. 2004, 16, 588-593.
10. European Medicines Agency - HMPC (Committee on Herbal Medicinal Products). Public statement on the use of herbal medicinal products containing pulegone and menthofuran. Final, November 23, 2005.
11. Grundy, D. L.; Still, C. C. Inhibition of acetylcholinesterases by pulegone-1,2-epoxide. Pestic. Biochem. Physiol. 1985, 23, 383-388.
12. (12) Siano, F.; Catalfamo, M.; Cautela, D.; Servillo, L.; Castaldo, D. Analysis of pulegone and its enanthiomeric distribution, in mintflavoured food products. Food Addit. Contam. 2005, 22, 197-203. (Pubitemid 40778717)
13. Bicchi, C.; Frattini, C. Quantitative determination of minor components in essential oils: determination of pulegone in peppermint oils. J. Chromatogr. A 1980, 190, 471-474.
14. Schulz, H.; Baranska, M. Identification and quantification of valuable plant substances by IR and Raman spectroscopy. Vib. Spectros. 2007, 43, 13-25.
15. Mirghani, M. E. S.; Che Man, Y. B. A new method for determining gossypol in cottonseed oil by FTIR spectroscopy. J. Am. Oil Chem. Soc. 2003, 80, 625-628.
16. Wilson, N. D.; Ivanova, M. S.; Watt, R. A.; Moffat, A. C. The quantification of citral in lemongrass and lemon oils by near-infrared spectroscopy, J. Pharm. Pharmacol. 2002, 54, 1257-1263.
17. De Nardo, T.; Shirom.a-K.ian, C; Halim, Y.; Francis, D.; RodríguezSaona, L. E. Rapid and simultaneous determination of lycopene and β-carotene contents in tomato juice by infrared spectroscopy. J. Agric. Food Chem. 2009, 57, 1105-1112.
18. Bombarda, I.; Dupuy, N.; Le Van Da, J.-P.; Gaydou, E. M, Comparative chemometric analyses of geographic origins and compositions of lavandin var. Grosso essential oils by mid infrared spectroscopy and gas chromatography, Anal. Chim. Acta. 2008, 613, 31-39.
19. Golmakani, M.-T.; Rezaei, K. Comparison of microwave-assisted hydrodistillation with the traditional hydrodistillation method in the extraction of essential oils from. Thymus vulgaris L. Food Chem. 2008, 109, 925-930.
20. Adams, R. P. Identification of Essential Oil Components by Gas Chromatography/Mass Spectrometry, 4th ed.; Allured Publishing Corporation: Carol Stream, IL, 2007.
21. Haaland, D. M.; Thomas, E. V. Partial least-squares methods for spectral analyses. 1. Relation to other quantitative calibration methods and the extraction of qualitative information. Anal. Chem. 1988, 60, 1193-1202.
22. Socrates, G. Infrared and Raman Characteristic Group Frequencies: Tables and Charts, 3rd ed.; John Wiley & Sons Ltd, Oxford, England, 2004.
23. Fuller, M. P.; Ritter, G. L.; Draper, C. S. Partial least-squares quantitative analysis of infrared spectroscopic data. Part II: Application to detergent analysis, Appl. Spectrosc. 1988, 42, 228236.