A new method for determining gossypol in cottonseed oil by FTIR spectroscopy

JAOCS, Journal of the American Oil Chemists' Society

Volumn 80, Issue 7, 2003, Pages 625-628

  Mirghani, M E S ^a   Che Man, Y B ^a  

^a UNIVERSITY PUTRA MALAYSIA   (Malaysia)

Author keywords

Cottonseed oil; FTIR spectroscopy; Gossypol; PLS

Indexed keywords

CALIBRATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; LEAST SQUARES APPROXIMATIONS; MATHEMATICAL MODELS; SODIUM CHLORIDE;

DATA MANIPULATION; GOSSYPOL; WET CHEMICAL METHODS;

COTTONSEED OIL;

MICROPUS;

EID: 0041386249     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-003-0749-2     Document Type: Article

References (22)

1. Kitts, D., Toxicity and Safety of Fats and Oils, in Bailey's Industrial Oil and Fat Products, edited by Y.H. Hui, 5th edn., John Wiley & Sons, New York, 1996, Vol. 1, p. 256.
2. Jones, L.A., and C.C. King, Cottonseed Oil, in Ibid., Vol. 2, pp. 192-193.
3. Pons, W.A., Jr., C.L. Hoffpauir, and R.T. O'Connor, Determination of Total Gossypol Pigments in Cottonseed Oils, J. Am. Oil Chem. Soc. 28:8-12 (1951).
4. Pons, W.A., Jr., C.L. Hoffpauir, and R.T. O'Connor, Determination of Total Gossypol Pigments in Cottonseed Oils, Ibid., Vol. 2, p. 193.
5. Sonntag, N.O.V., Composition and Characteristics of Individual Fats and Oils, in Bailey's Industrial Oil and Fat Products, 2nd edn., edited by D. Swern, John Wiley & Sons, New York, 1979, Vol. 1, p. 289.
6. Calhoun, M.C., J.E. Huston, C.B. Calk, B.C. Baldwin, Jr., and S.W. Kuhlman, Cattle Research with Gossypol-Containing Feeds, in A Collection of Papers Addressing Gossypol Effects in Cattle, edited by L.A. Jones, D.H. Kinard, and J.S. Mills, National Cottonseed Products Association, Memphis, 1991, p. 39.
7. Chamkasem, N., and L.A. Johnson, Color Stability of Glandless Cottonseed Oil, J. Am. Oil Chem. Soc. 65:1778-1780 (1988).
8. Yabe, Y., S. Tan, T. Ninomya, and T. Okada, J. Food Hygiene Soc. Jpn. 25:264 (1984).
9. Yabe, Y., S. Tan, T. Ninomya, and T. Okada, Bailey's Industrial Oil and Fat Products, 5th edn., edited by Y.H. Hui, John Wiley amp; Sons, New York 1996, Vol. 2, p. 193.
10. Hanny, B.W., Gossypol, Flavonoid and Condensed Tannin Content of Cream and Yellow Anther of Five Cotton (Gossypium hirsutum L.) Cultivars, J. Agric. Food Chem. 28:504-506 (1980).
11. Nomeir, A.A., and M.B. Adou-Donia, Gossypol: High-Performance Liquid Chromatographic Analysis and Stability in Various Solvents, J. Am. Oil Chem. Soc. 59:546-549 (1982).
12. AOCS, Official Methods and Recommended Practices of the American Oil Chemists' Society, 4th edn., edited by D. Firestone, AOCS Press, Champaign, 1995, Method Ba 8-78.
13. Che Man, Y.B., and M.E.S. Mirghani, Rapid Determination of Moisture Content in Crude Palm Oil by Fourier Transform Infrared Spectroscopy, J. Am. Oil Chem. Soc. 77:631-637 (2000).
14. Che Man, Y.B., G. Setiowaty, and F.R. van de Voort, Determination of Iodine Value of Palm Oil by FTIR, Ibid. 76:693-699 (1999).
15. Lavine, B.K., Chemometrics, Anal. Chem. 70:209R-228R (1998).
16. George, W.O., and H.A. Willis, Computer Methods in UV, Visible and IR Spectroscopy, The Royal Society of Chemistry, London, United Kingdom, 1990, pp. 185-190.
17. Dubois, J., F.R. van de Voort, J. Sedman, A.A. Ismail, and H.R. Ramaswamy, Quantitative Fourier Infrared Analysis for Anisidine Value and Aldehydes in Thermally Stressed Oils, J. Am. Oil Chem. Soc. 73:787-794 (1996).
18. Haaland, D.M., and E.V. Thomas, Practical Least Square Methods for Spectral Analysis 1: Relation to Other Quantitative Calibration Methods and the Extraction of Quantitative Information, J. Anal. Chem. 60:1193-1201 (1988).
19. Nakanishi, K., and P.H. Solomon, Infrared Absorption Spectroscopy, 2nd edn., Holden-Day, San Francisco, 1977, pp. 1-5.
20. Bellamy, L.J., The Infrared Spectra of Complex Molecules, 3rd edn., Chapman & Hall, London, 1975, pp. 151-177.
21. Stuart, B. Modern Infrared Spectroscopy, edited by D.J. Ando, John Wiley & Sons, New York, 1996, 135 pp.
22. Fuller, M.P., G.L. Ritter, and C.S. Drapper, Partial Least-Squares Quantitative Analysis of Infrared Spectroscopic Data. Part II: Application to Detergent Analysis, Appl. Spectrosc. 42:228-236 (1988).