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u-components changes correspondingly in the porphyrin plane. This change in direction affects their coupling with motions of the ethyl substituents, leading to the observed NRVS differences of porphyrin core modes in different conformers. See: Lehnert, N., Sage, J. T., Scheidt, W. R., Sturhahn, W., and Zhao, J., manuscript in preparation.
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2- complexes for the purpose of detailed vibrational analyses.
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84
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77951545581
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Note
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h. In the case of S = 1/2 systems as considered here, spin polarization effects are usually small.
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