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The following abbreviations are used in this paper. sGC, soluble guanylate cyclase; NO, nitric oxide; mono, monoclinic; tri, triclinic; Porph, generalized porphyrin dianion; TpFPP, dianion of meso-p-fluorotetraphenylporphyrin; TPP, dianion of meso-tetraphenylporphyrin; 1-MeIm, 1-methylimidazole; R-Im, generalized substituted imidazole. Spectroscopic techniques: IR, infrared absorption spectroscopy; rR, resonance Raman spectroscopy; NRVS, nuclear resonance vibrational spectroscopy
-
The following abbreviations are used in this paper. sGC, soluble guanylate cyclase; NO, nitric oxide; mono, monoclinic; tri, triclinic; Porph, generalized porphyrin dianion; TpFPP, dianion of meso-p-fluorotetraphenylporphyrin; TPP, dianion of meso-tetraphenylporphyrin; 1-MeIm, 1-methylimidazole; R-Im, generalized substituted imidazole. Spectroscopic techniques: IR, infrared absorption spectroscopy; rR, resonance Raman spectroscopy; NRVS, nuclear resonance vibrational spectroscopy.
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SADABS
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39
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65549112280
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Universität Göttingen: Göttingen, Germany
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43
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39749160177
-
-
Although the thermal parameters of the second orientation have been refined as equal to the first orientation, there is evidence (especially in structures above 100 K) of electron density between the first and second orientations that can not be properly modeled as two or even three atoms
-
Although the thermal parameters of the second orientation have been refined as equal to the first orientation, there is evidence (especially in structures above 100 K) of electron density between the first and second orientations that can not be properly modeled as two or even three atoms.
-
-
-
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44
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39749110433
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-
Attempts were made to refine the 1-methylimidazole with two rigid bodies or a disorder model with isotropic thermal parameters with no improvement to the structure
-
Attempts were made to refine the 1-methylimidazole with two rigid bodies or a disorder model with isotropic thermal parameters with no improvement to the structure.
-
-
-
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45
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39749170094
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-
An analysis of the NRVS vibrational spectra of tri-[Fe(TpFPP)(NO, 1-MeIm, and mono-[Fe(TpFPP)(NO)1-MeIm, and the 100 K structures have been previously reported.23
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23
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48
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33645870443
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55
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39749139891
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-
Standard deviations are calculated on the assumption that the values are taken from the same population
-
Standard deviations are calculated on the assumption that the values are taken from the same population.
-
-
-
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56
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33847089375
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Scheidt, W. R.; Brinegar, A. C.; Ferro, E. B.; Kirner, J. F. J. Am. Chem. Soc. 1977, 99, 7315.
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57
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39749131413
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-
ORTEP diagrams of tri-[Fe(TpFPP)(NO)(1-MeIm)] at each reported temperature (see Table 3) are displayed in the Supporting Information.
-
ORTEP diagrams of tri-[Fe(TpFPP)(NO)(1-MeIm)] at each reported temperature (see Table 3) are displayed in the Supporting Information.
-
-
-
-
58
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39749107073
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During the 350 K data collection for tri-[Fe(TpFPP)(NO)(1-MeIm)], sample decay became evident. The reported structure is based on a subset of the total reflections that represent 100% completeness to a resolution of 0.90 Å.
-
During the 350 K data collection for tri-[Fe(TpFPP)(NO)(1-MeIm)], sample decay became evident. The reported structure is based on a subset of the total reflections that represent 100% completeness to a resolution of 0.90 Å.
-
-
-
-
59
-
-
39749154514
-
-
3PP)(NO)(1-MeIm)] at each reported temperature (see Table 3) are displayed in the Supporting Information.
-
3PP)(NO)(1-MeIm)] at each reported temperature (see Table 3) are displayed in the Supporting Information.
-
-
-
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60
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39749151971
-
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The binding constants for the addition of an imidazole to a five-coordinate nitrosyl are known to be small and are summarized in ref 40. Neither the trans effect or the binding constant absolutely predict that the Fe-NIm bond will show a strong temperature dependence
-
Im bond will show a strong temperature dependence.
-
-
-
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61
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39749195280
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-
For example, a six-coordinate CO complex showed a 3.2% change in cell N. Silvernail, B. C. Noll, and W. R. Scheidt, work in progress.
-
For example, a six-coordinate CO complex showed a 3.2% change in cell volume. N. Silvernail, B. C. Noll, and W. R. Scheidt, work in progress.
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62
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39749094794
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2
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2
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63
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0003625523
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