Preparation of "Si-centered" chiral silanes by direct α-lithiation of methylsilanes

Chemistry - A European Journal

Volumn 16, Issue 13, 2010, Pages 4048-4062

  Däschlein, Christian ^a   Gessner, Viktoria H ^a   Strohmann, Carsten ^a  

^a TU DORTMUND UNIVERSITY   (Germany)

Author keywords

Chirality; Lithium; Organolithium compounds; Organosilicon; Structure elucidation

Indexed keywords

ALKYLLITHIUMS; ALTERNATIVE ROUTES; CHIRAL COMPOUNDS; CHIRAL SILANES; COMPUTATIONAL STUDIES; DESYM-METRIZATION; DIASTEREO-SELECTIVITY; EFFICIENT METHOD; HIGH YIELD; LITHIATION; METHYL GROUP; METHYLSILANES; OLIGOSILANES; ORGANOLITHIUM COMPOUNDS; ORGANOSILICONES; REPULSION EFFECTS; SILICON CENTERS; STRUCTURE ANALYSIS; STRUCTURE ELUCIDATION; STRUCTURE FORMATIONS; TRANSITION STATE; X RAY STRUCTURE ANALYSIS;

CHIRALITY; ELECTRON TRANSITIONS; ENANTIOMERS; HYDROCARBONS; LITHIUM; SILANES; SILICON; STEREOCHEMISTRY;

LITHIUM COMPOUNDS;

EID: 77950246389     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902551     Document Type: Article

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