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note
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n (A) was obtained in 55% yield. The NMR of 2 was not measured, since the compound was obtained in a small quantity and it decomposes rapidly when dissolved in hydrocarbons.
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3. RI = 0.0659 (l > 2σ(I)), wR2 = 0.1737 (ail data), GOF = 1.041.
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0031456187
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3 and in two coaggregates of t-BuLi with organolithium: (a) Williard, P. G.; Sun, C. J. Am. Chem. Soc. 1997, 119, 11693.
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0036471887
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(b) Hardman, N. J.; Twamley, B.; Slender, M.; Baldwin, R.; Hino, S.; Schiemenz, B.; Kauzlarich, S. M.; Power, P. P. J. Organomet. Chem. 2002, 643, 461.
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Schiemenz, B.6
Kauzlarich, S.M.7
Power, P.P.8
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note
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2).
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The green powders A and B were reacted with a variety of substrates. These reactions will be reported elsewhere.
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2)
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2).
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The reasons for these differences in the NMR chemical shifts of 3 and 1 are not yet understood and are under current study.
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33749868512
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Due to the extreme air and moisture sensitivity of 2, 3, A, and B, determination of their elemental analysis and melting point is not practical and therefore was not carried out.
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