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Volumn 25, Issue 20, 2006, Pages 4719-4721

Novel aggregation motif of gem-dilithiosilanes: Coaggregation of two R 2SiLi2 molecules with two RLi molecules

Author keywords

[No Author keywords available]

Indexed keywords

CO-AGGREGATION; GEM-DILITHIOSILANES; MERCURY PRECURSORS;

EID: 33749840707     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060469o     Document Type: Article
Times cited : (22)

References (32)
  • 24
    • 33749856239 scopus 로고    scopus 로고
    • note
    • n (A) was obtained in 55% yield. The NMR of 2 was not measured, since the compound was obtained in a small quantity and it decomposes rapidly when dissolved in hydrocarbons.
  • 25
    • 33749857375 scopus 로고    scopus 로고
    • note
    • 3. RI = 0.0659 (l > 2σ(I)), wR2 = 0.1737 (ail data), GOF = 1.041.
  • 26
    • 0031456187 scopus 로고    scopus 로고
    • 3 and in two coaggregates of t-BuLi with organolithium: (a) Williard, P. G.; Sun, C. J. Am. Chem. Soc. 1997, 119, 11693.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 11693
    • Williard, P.G.1    Sun, C.2
  • 28
    • 33749833587 scopus 로고    scopus 로고
    • note
    • 2).
  • 29
    • 33749828885 scopus 로고    scopus 로고
    • note
    • The green powders A and B were reacted with a variety of substrates. These reactions will be reported elsewhere.
  • 30
    • 33749871983 scopus 로고    scopus 로고
    • 2)
    • 2).
  • 31
    • 33749834180 scopus 로고    scopus 로고
    • note
    • The reasons for these differences in the NMR chemical shifts of 3 and 1 are not yet understood and are under current study.
  • 32
    • 33749868512 scopus 로고    scopus 로고
    • note
    • Due to the extreme air and moisture sensitivity of 2, 3, A, and B, determination of their elemental analysis and melting point is not practical and therefore was not carried out.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.