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13444262085
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CCDC-247482 (1), -247483 (2), and -247484 (3) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44) 1223-336-033; or deposit@ccdc.cam.ac.uk).
-
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37
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13444291270
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note
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w = 0.2137 (all data), GOF = 0.759.
-
-
-
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38
-
-
13444256186
-
-
note
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w = 0.1562(all data), GOF = 0.8. As shown in Figure 2, the Si-H hydrogen atoms are disordered and occupy two sites, each with a refined occupancy ratio of 50:50.
-
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39
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13444306363
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note
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The X-ray molecular structure of 3 will be reported elsewhere.
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13444278711
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3Si was previously observed in the photolysis of the corresponding silylmercury compound: D. Bravo-Zhivotovskii, M. Yuzefovich, N. Sigal, K. Klinkhammer, B. Tumanskii, A. Shames, Y. Apeloig, Angew. Chem. 2002, 114, 671-673; Angew. Chem. Int. Ed. 2002, 41, 649-651.
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0037084224
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3Si was previously observed in the photolysis of the corresponding silylmercury compound: D. Bravo-Zhivotovskii, M. Yuzefovich, N. Sigal, K. Klinkhammer, B. Tumanskii, A. Shames, Y. Apeloig, Angew. Chem. 2002, 114, 671-673; Angew. Chem. Int. Ed. 2002, 41, 649-651.
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43
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13444293040
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note
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The Supporting Information consists of the EPR spectra observed during irradiation of 1 and 2 and the simulated (using the SimFonia software) EPR spectra of silyl radicals substituted by two or three Li atoms.
-
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44
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0003921563
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McGraw-Hill, New York, cha. 10
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|