Intermolecular chirality transfer from silicon to carbon: Interrogation of the two-silicon cycle for Pd-catalyzed hydrosilylation by stereoisotopochemical crossover

Journal of the American Chemical Society

Volumn 129, Issue 3, 2007, Pages 502-503

  Rendler, Sebastian ^a   Oestreich, Martin ^a   Butts, Craig P ^b   Lloyd Jones, Guy C ^b  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; PALLADIUM; SILICON;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL BOND; CHIRALITY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; HYDROSILYLATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY; STEREOISOMERISM;

CARBON; CATALYSIS; HETEROCYCLIC COMPOUNDS; MOLECULAR STRUCTURE; PALLADIUM; SILICON; STEREOISOMERISM;

EID: 33846456984     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja067780h     Document Type: Article

References (12)

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2. Schmidt, D. R.; O'Malley, S. J.; Leighton, J. J. Am. Chem. Soc. 2003, 125, 1190.
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4. Rendler, S.; Auer, G.; Keller, M.; Oestreich, M. Adv. Synth. Catal. 2006, 348, 1171.
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7. See Supporting Information for full details.
8. More O'Ferrall, R. A. J. Chem. Soc. B 1970, 785.
9. 2b was used instead of 2a because of the slightly diminished diastereo-selectivity allowing for the detection and separation of all four possible stereoisomers.
10. 2H]-2b through silane exchange.
11. Zhang, Q.; Curran, D. P. Chem.-Eur. J. 2005, 11, 4866.
12. See for example: Rendler, S.; Auer, G.; Oestreich, M. Angew. Chem., Int. Ed. 2005, 44, 7620.