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51
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DNA-based asymmetric catalysis: sequence-dependent rate acceleration and enantioselectivity
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Illustrates the rate-accelerating potential and stereochemical impact of the second coordination sphere of DNA on embedded Lewis-acid catalysts.
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Boersma A.J., Klijn J.E., Feringa B.L., and Roelfes G. DNA-based asymmetric catalysis: sequence-dependent rate acceleration and enantioselectivity. J Am Chem Soc 130 (2008) 11783-11790. Illustrates the rate-accelerating potential and stereochemical impact of the second coordination sphere of DNA on embedded Lewis-acid catalysts.
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53
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DNA-based catalytic enantioselective Michael reactions in water
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Coquière D., Feringa B.L., and Roelfes G. DNA-based catalytic enantioselective Michael reactions in water. Angew Chem, Int Ed FIELD Full Journal Title: Angewandte Chemie, International Edition 46 (2007) 9308-9311
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DNA-based hydrolytic kinetic resolution of epoxides
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Dijk E.W., Feringa B.L., and Roelfes G. DNA-based hydrolytic kinetic resolution of epoxides. Tetrahedron Asymmetry 19 (2008) 2374-2377
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Tetrahedron Asymmetry
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Dijk, E.W.1
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DNA-mediated enantioselective carbon-fluorine bond formation
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Shibata N., Yasui H., Nakamura S., and Toru T. DNA-mediated enantioselective carbon-fluorine bond formation. Synlett (2007) 1153-1157
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Enantioselective Friedel-Crafts reactions in water using a DNA-based catalyst
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Boersma A.J., Feringa B.L., and Roelfes G. Enantioselective Friedel-Crafts reactions in water using a DNA-based catalyst. Angew Chem Int Ed 48 (2009) 3346-3348
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DNA-enhanced peroxidase activity of a DNA-aptamer-hemin complex
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Travascio P., Li Y., and Sen D. DNA-enhanced peroxidase activity of a DNA-aptamer-hemin complex. Chem Biol 5 (1998) 505-517
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Phosphine containing oligonucleotides for the development of metallodeoxyribozymes
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Ropartz L., Meeuwenoord N.J., van der Marel G.A., van Leeuwen P.W., Slawin A.M., and Kamer P.C. Phosphine containing oligonucleotides for the development of metallodeoxyribozymes. Chem Commun (2007) 1556-1558
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Ropartz, L.1
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60
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Modular assembly of novel DNA-based catalysts
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Oltra N.S., and Roelfes G. Modular assembly of novel DNA-based catalysts. Chem Commun (2008) 6039-6041
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Chem Commun
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Allylic amination by a DNA-diene-iridium(I) hybrid catalyst
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Fournier P., Fiammengo R., and Jäschke A. Allylic amination by a DNA-diene-iridium(I) hybrid catalyst. Angew Chem Int Ed 48 (2009) 4426-4429
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Fournier, P.1
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Rational design of a structural and functional nitric oxide reductase
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Outstanding example of the computational design of an artificial metalloenzyme.
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Yeung N., Lin Y.-W., Gao Y.-G., Zhao X., Russell B.S., Lei L., Miner K.D., Robinson H., and Lu Y. Rational design of a structural and functional nitric oxide reductase. Nature (2009) 1-6. Outstanding example of the computational design of an artificial metalloenzyme.
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Nature
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Yeung, N.1
Lin, Y.-W.2
Gao, Y.-G.3
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63
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Rationally tuning the reduction potential of a single cupredoxin beyond the natural range
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Interesting work on the varying of the redox potentials of a metalloenzyme by genetically modifying the primary and secondary coordination sphere.
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Marshall N.M., Garner D.K., Wilson T.D., Gao Y.-G., Robinson H., Nilges M.J., and Lu Y. Rationally tuning the reduction potential of a single cupredoxin beyond the natural range. Nature 461 (2009) 113-116. Interesting work on the varying of the redox potentials of a metalloenzyme by genetically modifying the primary and secondary coordination sphere.
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Nature
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Marshall, N.M.1
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