Kinetic and thermodynamic analysis of processes relevant to initiation of olefin metathesis by ruthenium phosphonium alkylidene catalysts

Journal of the American Chemical Society

Volumn 132, Issue 8, 2010, Pages 2784-2794

  Leitao, Erin M ^a   Van Der Eide, Edwin F ^a   Romero, Patricio E ^a   Piers, Warren E ^a   McDonald, Robert ^b  

^a UNIVERSITY OF CALGARY   (Canada)

^b UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLIDENES; BINDING RATE; CATALYST PRECURSORS; CATALYTIC AMOUNTS; CHLORIDE ABSTRACTION; INITIATION PROCESS; INITIATION RATE; KINETIC AND THERMODYNAMIC PARAMETERS; OLEFIN METATHESIS; OLEFIN METATHESIS REACTIONS; PSEUDO-FIRST-ORDER; SECOND ORDERS; STERIC BULK; THERMO DYNAMIC ANALYSIS;

CATALYSTS; CHLORINE COMPOUNDS; ETHYLENE; MONOMERS; REACTION RATES; RUTHENIUM; THERMOANALYSIS; THERMODYNAMICS;

CATALYSIS;

ALKENE; ALKYNE DERIVATIVE; AMPHOLYTE; CHLORIDE; ETHYLENE; MONOMER; PHOSPHONIUM DERIVATIVE; RUTHENIUM; STYRENE DERIVATIVE;

ADDITION REACTION; ARTICLE; BINDING AFFINITY; CATALYST; DIMERIZATION; KINETICS; RING CLOSING METATHESIS; SUBSTITUTION REACTION; THERMODYNAMICS;

EID: 77649312902     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja910112m     Document Type: Article

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