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6 have been described as metathesis-active precursor complexes recently: A. Fürstner, M. Picquet, C. Bruneau, P. H. Dixneuf, Chem. Comm. 1998, 1315-1316;
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note
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-3. c) Cristallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-112064 (2d) and CCDC-112065 (4a). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 IEZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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1H NMR spectra were measured in a sealed high-pressure NMR tube under a pressure of 10 bar Ar.
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1H NMR spectra were measured in a sealed high-pressure NMR tube under a pressure of 10 bar Ar.
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32
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33747538655
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note
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2 (0.45 mL). After addition of degassed cyclooctene (81.4 μL, 625 μmol; > 99.5% (GC); Fluka) the NMR tube was sealed and shaken. The NMR spectra were recorded at 23°C on a Bruker DRX 500 spectrometer at 500 MHz. b) Polymerization of cyclooctene with 1a (0.05 μmol; Strem Chemicals Inc.) as catalyst was carried out under identical reaction conditions.
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33
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The product distribution was analyzed by GC-MS
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The product distribution was analyzed by GC-MS.
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34
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