The First Highly Active, Halide-Free Ruthenium Catalyst for Olefin Metathesis

Organometallics

Volumn 22, Issue 18, 2003, Pages 3634-3636

  Conrad, Jay C ^a   Amoroso, Dino ^a   Czechura, Pawel ^a   Yap, Glenn P A ^a   Fogg, Deryn E ^a,b  

^a UNIVERSITY OF OTTAWA   (Canada)

^b Promerus LLC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; OLEFINS; RUTHENIUM; SOLVENTS;

METATHESIS;

COMPLEXATION;

EID: 0042324047     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030494j     Document Type: Article

References (28)

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22. a values: perfluorophenol, 5.52 (Birchall, J. M.; Haszeldine, R. N. J. Chem. Soc. 1959, 3653); phenol, 10; tert-butyl alcohol, 18 (Streitwieser, A. J.; Heathcock, C. H. Introduction to Organic Chemistry, 2nd ed.; McMillan: New York, 1981).
23. a values: perfluorophenol, 5.52 (Birchall, J. M.; Haszeldine, R. N. J. Chem. Soc. 1959, 3653); phenol, 10; tert-butyl alcohol, 18 (Streitwieser, A. J.; Heathcock, C. H. Introduction to Organic Chemistry, 2nd ed.; McMillan: New York, 1981).
24. The utility of thallium salts in such reactions is described in ref 12.
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27. Turnover numbers are considerably increased for cross-metathesis or RCM in neat substrate, with TON values for 6a in some cases exceeding 200 000. Dinger, M. B.; Mol, J. C. Adv. Synth. Catal. 2002, 344, 671.
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