Analysis of a pentacoordinate iron dicarbonyl as synthetic analogue of the Hmd or mono-iron hydrogenase active site

Chemistry - A European Journal

Volumn 16, Issue 10, 2010, Pages 3083-3089

  Liu, Tianbiao ^a   Li, Bin ^c   Popescu, Codrina V ^b   Bilko, Andrey ^b   Pérez, Lisa M ^a   Hall, Michael B ^a   Darensbourg, Marcetta Y ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b URSINUS COLLEGE   (United States)

^c TIANJIN UNIVERSITY   (China)

Author keywords

Hydrogenases; Iron; Non innocent ligand co exchange; Synthetic analogues

Indexed keywords

ABSORPTION FREQUENCIES; ACTIVE SITE; CO ATMOSPHERE; CO EXCHANGE; CO UPTAKE; CO-GROUP; DELOCALIZATIONS; DFT CALCULATION; DICARBONYLS; GEOMETRICAL DISTORTION; HYDROGENASES; IRON CENTERS; ISOMER SHIFTS; LEWIS ACIDITY; NON-INNOCENCE; SQUARE-PYRAMIDAL GEOMETRY; STRONG ACIDS; SYNTHETIC ANALOGUES;

BIOMIMETICS; DENSITY FUNCTIONAL THEORY; IRON COMPOUNDS; MOLYBDENUM COMPOUNDS; PROBABILITY DENSITY FUNCTION; SULFUR COMPOUNDS;

LIGANDS;

HYDROGENASE; IRON DERIVATIVE; IRON HYDROGENASE; IRON SULFUR PROTEIN; LIGAND;

ARTICLE; BINDING SITE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROCHEMISTRY; METABOLISM; X RAY CRYSTALLOGRAPHY;

BINDING SITES; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; ELECTROCHEMISTRY; HYDROGENASE; IRON COMPOUNDS; IRON-SULFUR PROTEINS; LIGANDS; MOLECULAR STRUCTURE;

EID: 77649209702     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902684     Document Type: Article

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