Monoiron hydrogenase catalysis: Hydrogen activation with the formation of a dihydrogen, Fe-Hδ-⋯Hδ+-O, bond and methenyl-H4MPT+ triggered hydride transfer

Journal of the American Chemical Society

Volumn 131, Issue 31, 2009, Pages 10901-10908

  Yang, Xinzheng ^a   Hall, Michael B ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SITE; AVERAGE ERRORS; DENSITY FUNCTIONAL THEORY CALCULATIONS; DFT CALCULATION; DIHYDROGEN; DIHYDROGEN BONDS; DITHIOTHREITOL; HYDRIDE FORMATION; HYDRIDE TRANSFERS; HYDROGEN ACTIVATION; HYDROGENASES; IRON CENTERS; NEW MECHANISMS; PYRIDONES; RESTING STATE; VIBRATIONAL FREQUENCIES; WILD TYPES; X RAY CRYSTAL STRUCTURES;

DENSITY FUNCTIONAL THEORY; HYDROGEN; HYDROGEN BONDS; OXYGEN; PLASMA JETS; PROBABILITY DENSITY FUNCTION; PROTON TRANSFER; SULFUR; SULFUR COMPOUNDS;

CRYSTAL STRUCTURE;

DITHIOTHREITOL; HYDROGEN; HYDROGENASE; METHANOPTERIN; MONOIRON HYDROGENASE; N5,N10 METHENYL TETRAHYDROMETHANOPTERIN; OXYGEN; PYRIDINOL; SULFUR; UNCLASSIFIED DRUG;

ARTICLE; BINDING AFFINITY; CATALYSIS; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ENZYME ACTIVATION; ENZYME ACTIVE SITE; FREQUENCY ANALYSIS; HYDROGEN BOND; HYDROGENATION; PROTON TRANSPORT; STEADY STATE; WILD TYPE; X RAY ANALYSIS;

CATALYSIS; CATALYTIC DOMAIN; HYDROGEN; HYDROGENASE; IRON-SULFUR PROTEINS; PROTEIN CONFORMATION; PTERINS;

EID: 68249161930     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja902689n     Document Type: Article

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