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Chemistry - A European Journal

Volumn 16, Issue 10, 2010, Pages 2997-3000

Squaraine-based [2] rotaxanes that function as visibly active molecular switches

(3) Hsueh, Sheng Yao a Lai, Chien Chen b Chiu, Sheng Hsien a

a NATIONAL TAIWAN UNIVERSITY (Taiwan)

b NATIONAL CHUNG HSING UNIVERSITY (Taiwan)

Author keywords

Bipyridinium ions; Molecular cages; Molecular switches; Rotaxanes; Squaraines

Indexed keywords

BIPYRIDINIUM; BIPYRIDINIUM IONS; MOLECULAR SWITCHES; ROTAXANES; SQUARAINES;

CYCLOBUTANE DERIVATIVE; PHENOL DERIVATIVE; PYRIDINIUM DERIVATIVE; ROTAXANE; SQUARAINE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; FLUORESCENCE;

CYCLOBUTANES; FLUORESCENCE; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; PHENOLS; PYRIDINIUM COMPOUNDS; ROTAXANES;

EID: 77649208377 PISSN: 09476539 EISSN: 15213765 Source Type: Journal
DOI: 10.1002/chem.200903304 Document Type: Article

Times cited : (35)

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- 4] as surrounding the squaraine station, in actuality this macrocyclic unit shuttles between the two stations, but with a preference for the squaraine moiety because of stronger noncovalenl interactions. A longer alkyl spacer provides a greater energy barrier to shuttling, thereby reducing the rate of translocation
- 4] as surrounding the squaraine station, in actuality this macrocyclic unit shuttles between the two stations, but with a preference for the squaraine moiety because of stronger noncovalenl interactions. A longer alkyl spacer provides a greater energy barrier to shuttling, thereby reducing the rate of translocation.

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