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For this synthetic approach, please refer to
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33
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62149097273
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Data for [2]rotaxane 17-H·2PF6: mp 105-106 °C; 1H NMR (400 MHz, CDCl3, δ, 1.34 (s, 18H, 1.37 (s, 18H, 3.65-3.69 (m, 16H, 3.80-3.98 (br, 4H, 4.22-4.32 (m, 4H, 5.47 (br, 2H, 5.86 (br, 2H, 6.22-6.38 (br, 2H, 6.92 (s, 8H, 7.05 (s, 2H, 7.26(s, 2H, 7.35-7.39 (br, 2H, 7.40 (s, 1H, 7.53 (s, 1H, 7.80 (d, J, 8 Hz, 2H, 8.11-8.19 (br, 2H, 8.57-8.61 (br, 2H, 13C NMR (100 MHz, CDCl3, δ, 31.3, 31.5, 35.0, 35.0, 44.1, 45.8, 65.0, 69.8, 70.5, 73.4, 121.9, 122.3, 123.6, 124.2, 125.0, 127.9, 128.7, 128.8, 131.0,132.5, 134.5, 136.7, 140.1,143.6, 151.2, 152.5, 153.8, 155.4. HR-MSESI, m/z calcd for [17-H-PF6, C67H 92N4O6PF6 1193.6659, found 1193.6659; [17-H]2+ C67H92N 4O6 524.3509, found 524.3508. Data for Dumbbell 18-H·2PF
-
4 316.2409, found 316.2408.
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34
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0030691058
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For other molecular switches that can be operated through changes in solvent polarity, see: a
-
For other molecular switches that can be operated through changes in solvent polarity, see: (a) Lane, A. S.; Leigh, D. A.; Murphy, A. J. Am. Chem. Soc. 1997, 119, 11092-11093.
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35
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0037415991
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36
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30744459380
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Chiu, S.-H.7
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