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4544369310
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4]MeOH, which indicates a lower occupancy of the succinamide station in these solvents.
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40
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37049083994
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4544317999
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note
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- where the macrocycle is situated over the succinamide station while simultaneously hydrogen bonding to the phenolate anion.
-
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-
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42
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-
4544376998
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note
-
7]DMF (0.6 mL) as solvent at 298 K. The base-induced shuttling in the rotaxane is rapid on the NMR timescale (the spectrum shown in Figure 1d is immediately apparent and not time dependent). Shuttling away from a succinamide binding site in a similar rotaxane has been shown to occur on the micro-second timescale. [13a,b]
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