Attachment of a hydrogen-bonding carboxylate side chain to an [FeFe]- hydrogenase model complex: Influence on the catalytic mechanism

Chemistry - A European Journal

Volumn 16, Issue 8, 2010, Pages 2537-2546

  Gao, Weiming ^a   Sun, Junliang ^a   Åkermark, Torbjörn ^b   Li, Mingrun ^a   Eriksson, Lars ^a   Sun, Licheng ^b   Åkermark, Björn ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

^b ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

Electrochemistry; Electron transfer; Enzyme model; Ironhydrogenase; Proton reduction

Indexed keywords

ACIDIC CONDITIONS; AQUEOUS SOLUTIONS; ASCORBIC ACIDS; BISPHOSPHINE; CATALYTIC MECHANISMS; COMPLEX 1; ELECTROCHEMICAL STUDIES; ELECTRON TRANSFER; ENZYME MODELS; HYDROGEN BONDINGS; HYDROGEN EVOLUTION; HYDROGENASES; IN-SITU IR; IRONHYDROGENASE; MODEL COMPLEXES; ONLINE MASS SPECTROMETRY; PROTON REDUCTION; PROTONATED SPECIES; PURE STATE; REDUCTION OF PROTONS; RU(BPY); SIDE CHAINS; THREE-COMPONENT SYSTEM; TRIFLIC ACIDS; VISIBLE LIGHT;

CARBOXYLATION; CARBOXYLIC ACIDS; ELECTROCHEMISTRY; ELECTRON TRANSITIONS; ENZYMES; HYDROGEN; HYDROGEN BONDS; KETONES; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC ACIDS; PROTONATION; PROTONS;

REDUCTION;

CARBOXYLIC ACID; HYDROGENASE; IRON; IRON HYDROGENASE; IRON SULFUR PROTEIN; ORGANOMETALLIC COMPOUND;

ARTICLE; BINDING SITE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROCHEMISTRY; HYDROGEN BOND; INFRARED SPECTROPHOTOMETRY; METABOLISM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

BINDING SITES; CARBOXYLIC ACIDS; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; ELECTROCHEMISTRY; HYDROGEN BONDING; HYDROGENASE; IRON; IRON-SULFUR PROTEINS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; SPECTROPHOTOMETRY, INFRARED;

EID: 77049106133     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902278     Document Type: Article

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