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Volumn 26, Issue 16, 2007, Pages 3976-3984

Synthesis of carboxylic acid-modified [FeFe]-hydrogenase model complexes amenable to surface immobilization

Author keywords

[No Author keywords available]

Indexed keywords

AMINO-FUNCTIONALIZED MONOLAYERS; HYDROGENASE MODEL; SURFACE IMMOBILIZATION;

EID: 34547771585     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7003354     Document Type: Article
Times cited : (115)

References (52)
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    • Tard, C.; Liu, X.; Ibrahim, S. K.; Bruschi, M.; De Gioia, L.; Davies, S. C.; Yang, X.; W. L.-S.; Sawers, G.; Pickett, C. J. Nature 2005, 433, 610-613.
    • (d) Tard, C.; Liu, X.; Ibrahim, S. K.; Bruschi, M.; De Gioia, L.; Davies, S. C.; Yang, X.; W. L.-S.; Sawers, G.; Pickett, C. J. Nature 2005, 433, 610-613.
  • 39
    • 84858107539 scopus 로고    scopus 로고
    • 6) reveals quantitative conversion of the -COOH to -CONHPh within 15 min. Isolated yields are lower as a result of difficulties separating the amide product from carbodiimide-derived side products.
    • 6) reveals quantitative conversion of the -COOH to -CONHPh within 15 min. Isolated yields are lower as a result of difficulties separating the amide product from carbodiimide-derived side products.
  • 41
    • 84858108089 scopus 로고    scopus 로고
    • 2}.
    • 2}.
  • 42
    • 34547762089 scopus 로고    scopus 로고
    • The reduction potentials of complexes 2 and 5 have been previously reported ref 13
    • The reduction potentials of complexes 2 and 5 have been previously reported (ref 13).
  • 44
    • 34547783104 scopus 로고    scopus 로고
    • Additional features in the CV of complexes 1 and 2 likely arise from the redox activity of the carboxylic acid moiety itself. A CV of 2-carboxy-1,3-propanedithiol is included in the Supporting Information.
    • Additional features in the CV of complexes 1 and 2 likely arise from the redox activity of the carboxylic acid moiety itself. A CV of 2-carboxy-1,3-propanedithiol is included in the Supporting Information.
  • 46
    • 33750285709 scopus 로고    scopus 로고
    • Aguirre de Career, I.; DiPasquale, A.; Rheingold, A. L.; Heinekey, D. M. Inorg. Chem. 2006, 45, 8000-8002.
    • Aguirre de Career, I.; DiPasquale, A.; Rheingold, A. L.; Heinekey, D. M. Inorg. Chem. 2006, 45, 8000-8002.
  • 48
    • 84858088795 scopus 로고    scopus 로고
    • - appears (see Supporting Information).
    • - appears (see Supporting Information).
  • 49
    • 34547756229 scopus 로고    scopus 로고
    • Additional support for this hypothesis is provided by the changes in the relative peak heights of the two reductions at -2.44 and -2.67 V at different scan rates: At faster scan rates (> 500 mV/s, the -2.44 V peak dominates, while the two peak heights are nearly identical at slow scan rates 100 mV/s, See Supporting Information for the corresponding voltammograms
    • Additional support for this hypothesis is provided by the changes in the relative peak heights of the two reductions at -2.44 and -2.67 V at different scan rates: At faster scan rates (> 500 mV/s), the -2.44 V peak dominates, while the two peak heights are nearly identical at slow scan rates (100 mV/s). See Supporting Information for the corresponding voltammograms.
  • 50
    • 0004150157 scopus 로고
    • Program for Crystal Structure Solution; Institut für Anorganische Chemie der Universität: Gottingen, Germany
    • (a) Sheldrick, G. SHELXS-97: Program for Crystal Structure Solution; Institut für Anorganische Chemie der Universität: Gottingen, Germany, 1977.
    • (1977) SHELXS-97
    • Sheldrick, G.1
  • 51
    • 34547775638 scopus 로고    scopus 로고
    • SAINT-PLUS, version 6.02; Bruker: Madison, WI, 1999
    • (b) SAINT-PLUS, version 6.02; Bruker: Madison, WI, 1999.
  • 52
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    • SHELXTL, version 6.1; Bruker: Madison, WI, 1998
    • (c) SHELXTL, version 6.1; Bruker: Madison, WI, 1998.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.