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84858107539
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6) reveals quantitative conversion of the -COOH to -CONHPh within 15 min. Isolated yields are lower as a result of difficulties separating the amide product from carbodiimide-derived side products.
-
6) reveals quantitative conversion of the -COOH to -CONHPh within 15 min. Isolated yields are lower as a result of difficulties separating the amide product from carbodiimide-derived side products.
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40
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84858108089
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2}.
-
2}.
-
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42
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34547762089
-
-
The reduction potentials of complexes 2 and 5 have been previously reported ref 13
-
The reduction potentials of complexes 2 and 5 have been previously reported (ref 13).
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24244476688
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34547783104
-
-
Additional features in the CV of complexes 1 and 2 likely arise from the redox activity of the carboxylic acid moiety itself. A CV of 2-carboxy-1,3-propanedithiol is included in the Supporting Information.
-
Additional features in the CV of complexes 1 and 2 likely arise from the redox activity of the carboxylic acid moiety itself. A CV of 2-carboxy-1,3-propanedithiol is included in the Supporting Information.
-
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45
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33947368523
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48
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84858088795
-
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- appears (see Supporting Information).
-
- appears (see Supporting Information).
-
-
-
-
49
-
-
34547756229
-
-
Additional support for this hypothesis is provided by the changes in the relative peak heights of the two reductions at -2.44 and -2.67 V at different scan rates: At faster scan rates (> 500 mV/s, the -2.44 V peak dominates, while the two peak heights are nearly identical at slow scan rates 100 mV/s, See Supporting Information for the corresponding voltammograms
-
Additional support for this hypothesis is provided by the changes in the relative peak heights of the two reductions at -2.44 and -2.67 V at different scan rates: At faster scan rates (> 500 mV/s), the -2.44 V peak dominates, while the two peak heights are nearly identical at slow scan rates (100 mV/s). See Supporting Information for the corresponding voltammograms.
-
-
-
-
50
-
-
0004150157
-
-
Program for Crystal Structure Solution; Institut für Anorganische Chemie der Universität: Gottingen, Germany
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34547747194
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SHELXTL, version 6.1; Bruker: Madison, WI, 1998
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(c) SHELXTL, version 6.1; Bruker: Madison, WI, 1998.
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-
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