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Volumn 81, Issue 11, 2009, Pages 2001-2012

Onium-tagged Ru complexes as universal catalysts for olefin metathesis reactions in various media

Author keywords

Aqueous media; Catalysis; Ionic liquids; Olefin metathesis; Ruthenium; Sustainable chemistry

Indexed keywords


EID: 73849142505     PISSN: 00334545     EISSN: 13653075     Source Type: Journal    
DOI: 10.1351/PAC-CON-08-10-13     Document Type: Conference Paper
Times cited : (14)

References (53)
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    • General reviews: (a) R. R. Schrock, A. H. Hoveyda. Angew. Chem., Int. Ed. 42, 4592 (2003);
    • General reviews: (a) R. R. Schrock, A. H. Hoveyda. Angew. Chem., Int. Ed. 42, 4592 (2003);
  • 9
    • 33746114221 scopus 로고    scopus 로고
    • For example, in a crude untreated product of diethyl diallylmalonate RCM catalyzed by 5 mol % of Grubbs I-generation catalyst, the theoretical amount of Ru is 90 mg per 5 mg of product (18000 ppm). After filtration of the crude reaction mixture, the Ru level was reduced to 59.7 ±0.50 mg per 5 mg (12000 ppm). Further purification of such crude metathesis products usually reduces Ru levels below 2000 ppm, see ref. [3a] and (b) K. McEleney, D. P. Allen, A. E. Holliday, C. M. Crudden. Org. Lett. 8, 2663 (2006).
    • (b) For example, in a crude untreated product of diethyl diallylmalonate RCM catalyzed by 5 mol % of Grubbs I-generation catalyst, the theoretical amount of Ru is 90 mg per 5 mg of product (18000 ppm). After filtration of the crude reaction mixture, the Ru level was reduced to 59.7 ±0.50 mg per 5 mg (12000 ppm). Further purification of such crude metathesis products usually reduces Ru levels below 2000 ppm, see ref. [3a] and (b) K. McEleney, D. P. Allen, A. E. Holliday, C. M. Crudden. Org. Lett. 8, 2663 (2006).
  • 10
    • 73849100288 scopus 로고    scopus 로고
    • Another solution to this problem might be based on the immobilization of a metathesis catalyst in a separate liquid or solid phase. For recent reviews, see: (a) A. H. Hoveyda, D. G. Gillingham, J. J. Van Veldhuizen, O. Kataoka, S. B. Garber, J. S. Kingsbury, J. P. A. Harrity. Org. Biomol. Chem. 2, 1 (2004);
    • Another solution to this problem might be based on the immobilization of a metathesis catalyst in a separate liquid or solid phase. For recent reviews, see: (a) A. H. Hoveyda, D. G. Gillingham, J. J. Van Veldhuizen, O. Kataoka, S. B. Garber, J. S. Kingsbury, J. P. A. Harrity. Org. Biomol. Chem. 2, 1 (2004);
  • 12
    • 73849089839 scopus 로고    scopus 로고
    • for related systems developed in our laboratories, see: c
    • for related systems developed in our laboratories, see: (c) K. Grela, K. Mennecke, U. Kunz, A. Kirschning. Synlett 2948 (2005);
    • (2005) Synlett , vol.2948
    • Grela, K.1    Mennecke, K.2    Kunz, U.3    Kirschning, A.4
  • 15
    • 33645456932 scopus 로고    scopus 로고
    • B. Cornils, W. A. Hermann Eds, Wiley-VCH, Weinheim
    • B. Cornils, W. A. Hermann (Eds.). Aqueous-Phase Organometallic Catalysis, Wiley-VCH, Weinheim (2004).
    • (2004) Aqueous-Phase Organometallic Catalysis
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    • 33845279312 scopus 로고    scopus 로고
    • 2, see: B. M. Novak, R. H. Grubbs. J. Am. Chem. Soc. 110, 960 (1988);
    • 2, see: B. M. Novak, R. H. Grubbs. J. Am. Chem. Soc. 110, 960 (1988);
  • 34
    • 58249119656 scopus 로고    scopus 로고
    • for a review on aqueous olefin metathesis, see
    • (l) for a review on aqueous olefin metathesis, see: D. Burtscher, K. Grela. Angew. Chem., Int. Ed. 48, 442 (2009).
    • (2009) Angew. Chem., Int. Ed , vol.48 , pp. 442
    • Burtscher, D.1    Grela, K.2
  • 42
    • 73849129878 scopus 로고    scopus 로고
    • PhD Thesis, Institute of Organic Chemistry, Warsaw
    • A. Michrowska. PhD Thesis, Institute of Organic Chemistry, Warsaw (2006).
    • (2006)
    • Michrowska, A.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.