Improved molecular weight control in ring-opening metathesis polymerization (ROMP) reactions with ru-based olefin metathesis catalysts using n. donors and acid: a kinetic and mechanistic investigation

Chemistry - A European Journal

Volumn 15, Issue 45, 2009, Pages 12435-12446

  Dunbar, Miles A ^a   Balof, Shawna L ^a   Labeaud, Lawrence J ^a   Yu, Bing ^a   Lowe, Andrew B ^b   Valente, Edward J ^c   Schanz, Hans Jörg ^a  

^a The University of Southern Mississippi   (United States)

^b UNIVERSITY OF NEW SOUTH WALES   (Australia)

^c UNIVERSITY OF PORTLAND   (United States)

Author keywords

Activation; Controlled polymerization; Inhibition; Olefin metathesis; Ruthenium

Indexed keywords

1-METHYLIMIDAZOLE; ACID-FREE; CONTROLLED POLYMERIZATION; CYCLOHEXYL; CYCLOOCTENE; DIMETHYLAMINOPYRIDINE; EFFICIENT CATALYSTS; GRUBBS' CATALYST; INITIATION MECHANISM; INITIATION RATE; LINEAR DEPENDENCY; NARROW MOLECULAR WEIGHT DISTRIBUTIONS; NOVEL CATALYSTS; OLEFIN METATHESIS; RING OPENING METATHESIS POLYMERIZATION; SUBSTRATE CONCENTRATIONS;

ACIDS; CATALYSTS; MIM DEVICES; MIXTURES; MOLECULAR WEIGHT DISTRIBUTION; OLEFINS; POLYMERS; REACTION RATES; RING OPENING POLYMERIZATION; RUTHENIUM; WEIGHT CONTROL;

CATALYSIS;

EID: 70849119727     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200901013     Document Type: Article

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