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The higher reaction temperatures required for chain transfer with catalysts 1 and 2 preclude the ROMP of Durham monomers due to the instability of the PA precursor polymer.
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0038003634
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note
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It is evident from the characterization data that the products of these reactions contain a significant portion of unmodified polymer; however, the amount of PA that is incorporated is clearly sufficient to affect the material properties.
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-
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47
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0038003635
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note
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Observance of these peaks was impossible for PS-b-PA samples due to the intense resonances from the phenyl protons of polystyrene.
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0038003636
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note
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This morphology is possibly a result of the fast evaporation of solvent that occurs when the films are made. With films that were formed by slowly evaporating the solvent (i.e., not spin coating), the spiked morphology was not observed. Rather, a highly disordered morphology with large, randomly placed crystal-like structures was seen.
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