Hydrogen-atom abstraction reactions by manganese(V)- and manganese(IV)-oxo porphyrin complexes in aqueous solution

Chemistry - A European Journal

Volumn 15, Issue 43, 2009, Pages 11482-11489

  Arunkumar, Chellaiah ^a   Lee, Yong Min ^a   Lee, Jung Yoon ^a   Fukuzumi, Shunichi ^a,b   Nam, Wonwoo ^a  

^a Ewha Womans University   (South Korea)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

Bioinorganic chemistry; C h activation; Hydrogen atom abstraction; Manganese; Porphyrinoids; Reaction mechanisms

Indexed keywords

ALKYLAROMATICS; AQUEOUS SOLUTIONS; ATOM ABSTRACTION; BIOINORGANIC CHEMISTRY; C-H ACTIVATION; C-H BOND; C-H BOND DISSOCIATION ENERGY; CH-BOND ACTIVATION; DIHYDROANTHRACENE; DISPROPORTIONATIONS; ELECTRON PROCESS; HYDROGEN ATOMS; KINETIC ISOTOPE EFFECTS; LINEAR CORRELATION; MANGANESE PORPHYRINS; ORGANIC SUBSTRATE; OXO COMPLEXES; OXO SPECIES; PORPHYRIN COMPLEXES; PORPHYRINOIDS; REACTION MECHANISMS; REACTIVE INTERMEDIATE; THIOANISOLE; TWO-ELECTRON OXIDATION PROCESS;

ABSTRACTING; ACTIVATION ANALYSIS; ATOMS; BIOCHEMISTRY; CHEMICAL ACTIVATION; CHEMICAL BONDS; HYDROCARBONS; HYDROGEN; ISOTOPES; MANGANESE COMPOUNDS; OXIDATION; PORPHYRINS; REACTION RATES; SUBSTRATES; SULFUR COMPOUNDS;

MANGANESE;

HYDROGEN; MANGANESE; OXIDE; PORPHYRIN; WATER;

ARTICLE; CHEMISTRY; OXIDATION REDUCTION REACTION; ULTRAVIOLET SPECTROPHOTOMETRY;

HYDROGEN; MANGANESE; OXIDATION-REDUCTION; OXIDES; PORPHYRINS; SPECTROPHOTOMETRY, ULTRAVIOLET; WATER;

EID: 70350504341     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200901362     Document Type: Article

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