Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium

Journal of the American Chemical Society

Volumn 131, Issue 41, 2009, Pages 14703-14712

  Tye, Jesse W ^a   Hartwig, John F ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AGOSTIC INTERACTIONS; ALKENE INSERTION; BADER'S ATOMS; BOND ORDERS; BRANCHED ALKANES; CARBON BOND; COMPUTATIONAL STUDIES; DFT CALCULATION; HYDROXO COMPLEXES; INSERTION PRODUCTS; LOCALIZED MOLECULAR ORBITALS; METAL-OXYGEN BONDS; METALLACYCLES; MIGRATORY INSERTION; NITROGEN BONDS; O-H BOND; RELATIVE RATES; RELATIVE STABILITIES; RHODIUM COMPLEXES; TRANSITION STATE;

AMINES; ETHYLENE; METALS; MOLECULAR ORBITALS; OXYGEN; PARAFFINS; PROPYLENE; RHODIUM; SULFUR COMPOUNDS;

RHODIUM COMPOUNDS;

CARBON; ETHYLENE; NITROGEN; OXYGEN; PROPYLENE; RHODIUM COMPLEX;

ARTICLE; ATOM; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONTROLLED STUDY; COVALENT BOND; DENSITY FUNCTIONAL THEORY;

EID: 70350057068     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja901945b     Document Type: Article

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