Thermodynamics of phosphine coordination to the [PNP]Rh(I) fragment: An example of the importance of reorganization energies in the assessment of metal-ligand 'bond strengths'

Journal of the American Chemical Society

Volumn 120, Issue 31, 1998, Pages 7806-7815

  Huang, Jinkun ^a   Haar, Christopher M ^a   Nolan, Steven P ^a   Marshall, William J ^a   Motoy, Kenneth G ^a  

^a DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; METAL; ORGANOMETALLIC COMPOUND; PHOSPHINE DERIVATIVE;

ARTICLE; CALORIMETRY; CHEMICAL STRUCTURE; ENTHALPY; STRUCTURE ANALYSIS; THERMODYNAMICS; X RAY ANALYSIS;

EID: 0032511352     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja974200v     Document Type: Article

References (26)

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5. 3, where Z may be carbon or a heteroatom, especially oxygen and nitrogen (e.g., phosphites and phosphoramides).
6. See the following and references therein: (a) McAuliffe, C. A.; Mackie, A. G. P-Donor Ligands. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; J. Wiley and Sons: New York, 1994; Vol. 6, p 2989. (b) Wilson, M. R.; Woska, D. C.; Prock, A.; Giering, W. P. Organometallics 1993, 12, 1742. (c) Caffery, M. L.; Brown, T. L. Inorg. Chem. 1991, 30, 3907. (d) Dunne, B. J.; Morris, R. B.; Orpen, A. G. J. Chem. Soc., Dalton Trans. 1991, 653. (e) Corbridge, D. E. C. Phosphorus. An Outline of its Chemistry, Biochemistry and Technology, 5th ed.; Elsevier: New York, 1995; Chapter 10.
7. See the following and references therein: (a) McAuliffe, C. A.; Mackie, A. G. P-Donor Ligands. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; J. Wiley and Sons: New York, 1994; Vol. 6, p 2989. (b) Wilson, M. R.; Woska, D. C.; Prock, A.; Giering, W. P. Organometallics 1993, 12, 1742. (c) Caffery, M. L.; Brown, T. L. Inorg. Chem. 1991, 30, 3907. (d) Dunne, B. J.; Morris, R. B.; Orpen, A. G. J. Chem. Soc., Dalton Trans. 1991, 653. (e) Corbridge, D. E. C. Phosphorus. An Outline of its Chemistry, Biochemistry and Technology, 5th ed.; Elsevier: New York, 1995; Chapter 10.
8. See the following and references therein: (a) McAuliffe, C. A.; Mackie, A. G. P-Donor Ligands. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; J. Wiley and Sons: New York, 1994; Vol. 6, p 2989. (b) Wilson, M. R.; Woska, D. C.; Prock, A.; Giering, W. P. Organometallics 1993, 12, 1742. (c) Caffery, M. L.; Brown, T. L. Inorg. Chem. 1991, 30, 3907. (d) Dunne, B. J.; Morris, R. B.; Orpen, A. G. J. Chem. Soc., Dalton Trans. 1991, 653. (e) Corbridge, D. E. C. Phosphorus. An Outline of its Chemistry, Biochemistry and Technology, 5th ed.; Elsevier: New York, 1995; Chapter 10.
9. See the following and references therein: (a) McAuliffe, C. A.; Mackie, A. G. P-Donor Ligands. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; J. Wiley and Sons: New York, 1994; Vol. 6, p 2989. (b) Wilson, M. R.; Woska, D. C.; Prock, A.; Giering, W. P. Organometallics 1993, 12, 1742. (c) Caffery, M. L.; Brown, T. L. Inorg. Chem. 1991, 30, 3907. (d) Dunne, B. J.; Morris, R. B.; Orpen, A. G. J. Chem. Soc., Dalton Trans. 1991, 653. (e) Corbridge, D. E. C. Phosphorus. An Outline of its Chemistry, Biochemistry and Technology, 5th ed.; Elsevier: New York, 1995; Chapter 10.
10. See the following and references therein: (a) McAuliffe, C. A.; Mackie, A. G. P-Donor Ligands. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; J. Wiley and Sons: New York, 1994; Vol. 6, p 2989. (b) Wilson, M. R.; Woska, D. C.; Prock, A.; Giering, W. P. Organometallics 1993, 12, 1742. (c) Caffery, M. L.; Brown, T. L. Inorg. Chem. 1991, 30, 3907. (d) Dunne, B. J.; Morris, R. B.; Orpen, A. G. J. Chem. Soc., Dalton Trans. 1991, 653. (e) Corbridge, D. E. C. Phosphorus. An Outline of its Chemistry, Biochemistry and Technology, 5th ed.; Elsevier: New York, 1995; Chapter 10.
11. (f) Levason, W. In The Chemistry of Organophosphorus Compounds; Hartley, F. R., Ed.; Wiley: New York, 1990; Vol. 1, Chapter 15. (g) McCauliffe, C. A. Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, U.K., 1987; Vol. 2, p 989. (h) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987; p 66. (i) Pignolet, L. H., Ed. Homogeneous Catalysis with Metal Phosphine Complexes; Plenum: New York, 1983. (k) Alyea, E. C.; Meek, D. W. Adv. Chem. Ser. 1982, 196.
12. (f) Levason, W. In The Chemistry of Organophosphorus Compounds; Hartley, F. R., Ed.; Wiley: New York, 1990; Vol. 1, Chapter 15. (g) McCauliffe, C. A. Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, U.K., 1987; Vol. 2, p 989. (h) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987; p 66. (i) Pignolet, L. H., Ed. Homogeneous Catalysis with Metal Phosphine Complexes; Plenum: New York, 1983. (k) Alyea, E. C.; Meek, D. W. Adv. Chem. Ser. 1982, 196.
13. (f) Levason, W. In The Chemistry of Organophosphorus Compounds; Hartley, F. R., Ed.; Wiley: New York, 1990; Vol. 1, Chapter 15. (g) McCauliffe, C. A. Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, U.K., 1987; Vol. 2, p 989. (h) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987; p 66. (i) Pignolet, L. H., Ed. Homogeneous Catalysis with Metal Phosphine Complexes; Plenum: New York, 1983. (k) Alyea, E. C.; Meek, D. W. Adv. Chem. Ser. 1982, 196.
14. (f) Levason, W. In The Chemistry of Organophosphorus Compounds; Hartley, F. R., Ed.; Wiley: New York, 1990; Vol. 1, Chapter 15. (g) McCauliffe, C. A. Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, U.K., 1987; Vol. 2, p 989. (h) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987; p 66. (i) Pignolet, L. H., Ed. Homogeneous Catalysis with Metal Phosphine Complexes; Plenum: New York, 1983. (k) Alyea, E. C.; Meek, D. W. Adv. Chem. Ser. 1982, 196.
15. (f) Levason, W. In The Chemistry of Organophosphorus Compounds; Hartley, F. R., Ed.; Wiley: New York, 1990; Vol. 1, Chapter 15. (g) McCauliffe, C. A. Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, U.K., 1987; Vol. 2, p 989. (h) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987; p 66. (i) Pignolet, L. H., Ed. Homogeneous Catalysis with Metal Phosphine Complexes; Plenum: New York, 1983. (k) Alyea, E. C.; Meek, D. W. Adv. Chem. Ser. 1982, 196.
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26. International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England, 1974; Vol. IV: (a) Table 2.2B; (b) Table 2.3.1.