-
4
-
-
33746216313
-
-
Selected recent reviews: (a)
-
Selected recent reviews: (a) Donohoe, T. J.; Orr, A. J.; Bingham, M. Angew. Chem., Int. Ed. 2006, 45, 2664-2670.
-
(2006)
Angew. Chem., Int. Ed.
, vol.45
, pp. 2664-2670
-
-
Donohoe, T.J.1
Orr, A.J.2
Bingham, M.3
-
5
-
-
33748544300
-
-
(b) Michaut, A.; Rodriguez, J. Angew. Chem., Int. Ed. 2006, 45, 5740-5750.
-
(2006)
Angew. Chem., Int. Ed.
, vol.45
, pp. 5740-5750
-
-
Michaut, A.1
Rodriguez, J.2
-
8
-
-
22744448499
-
-
(e)Nicolaou, K. C.; Bulger, P. G.; Sarlah, D. Angew. Chem., Int. Ed. 2005, 44, 4490-4527
-
(2005)
Angew. Chem., Int. Ed.
, vol.44
, pp. 4490-4527
-
-
Nicolaou, K.C.1
Bulger, P.G.2
Sarlah, D.3
-
11
-
-
64549162398
-
-
(a) Monfette, S.; Camm, K. D.; Gorelsky, S. I.; Fogg, D. E. Organometallics 2009, 28, 944-946.
-
(2009)
Organometallics
, vol.28
, pp. 944-946
-
-
Monfette, S.1
Camm, K.D.2
Gorelsky, S.I.3
Fogg, D.E.4
-
13
-
-
0042324047
-
-
(c) Conrad, J. C.; Amoroso, D.; Czechura, P.; Yap, G. P. A.; Fogg, D. E. Organometallics 2003, 22, 3634-3636.
-
(2003)
Organometallics
, vol.22
, pp. 3634-3636
-
-
Conrad, J.C.1
Amoroso, D.2
Czechura, P.3
Yap, G.P.A.4
Fogg, D.E.5
-
14
-
-
24144461226
-
-
(d) Conrad, J. C.; Parnas, H. H.; Snelgrove, J. L.; Fogg, D. E. J. Am. Chem. Soc. 2005, 127, 11882-11883.
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 11882-11883
-
-
Conrad, J.C.1
Parnas, H.H.2
Snelgrove, J.L.3
Fogg, D.E.4
-
15
-
-
29244463839
-
-
(e) Drouin, S. D.; Foucault, H. M.; Yap, G. P. A.; Fogg, D. E. Can. J. Chem. 2005, 83, 748-754.
-
(2005)
Can. J. Chem.
, vol.83
, pp. 748-754
-
-
Drouin, S.D.1
Foucault, H.M.2
Yap, G.P.A.3
Fogg, D.E.4
-
16
-
-
34948872733
-
-
For leading references, see ref 2c and: (a)
-
For leading references, see ref 2c and: (a) Gawin, R.; Makal, A.; Wozniak, K.; Mauduit, M.; Grela, K. Angew. Chem., Int. Ed. 2007, 46, 7206-7209.
-
(2007)
Angew. Chem., Int. Ed.
, vol.46
, pp. 7206-7209
-
-
Gawin, R.1
Makal, A.2
Wozniak, K.3
Mauduit, M.4
Grela, K.5
-
18
-
-
0012939456
-
-
(c) Denk, K.; Fridgen, J.; Herrmann, W. A. Adv. Synth. Catal. 2002, 344, 666-670.
-
(2002)
Adv. Synth. Catal.
, vol.344
, pp. 666-670
-
-
Denk, K.1
Fridgen, J.2
Herrmann, W.A.3
-
19
-
-
20344392171
-
-
(d) Halbach, T. S.; Mix, S.; Fischer, D.; Maechling, S.; Krause, J. O.; Sievers, C.; Blechert, S.; Nuyken, O.; Buchmeiser, M. R. J. Org. Chem. 2005, 70, 4687-4694, and references therein.
-
(2005)
J. Org. Chem.
, vol.70
, pp. 4687-4694
-
-
Halbach, T.S.1
Mix, S.2
Fischer, D.3
Maechling, S.4
Krause, J.O.5
Sievers, C.6
Blechert, S.7
Nuyken, O.8
Buchmeiser, M.R.9
-
20
-
-
33746410595
-
-
2 isomers. See: (a)
-
2 isomers. See: (a) Barbasiewicz, M.; Szadkowska, A.; Bujok, R.; Grela, K. Organometallics 2006, 25, 3599-3604.
-
(2006)
Organometallics
, vol.25
, pp. 3599-3604
-
-
Barbasiewicz, M.1
Szadkowska, A.2
Bujok, R.3
Grela, K.4
-
21
-
-
9144245653
-
-
(b) Ung, T.; Hejl, A.; Grubbs, R. H.; Schrodi, Y Organometallics 2004, 23, 5399-5401.
-
(2004)
Organometallics
, vol.23
, pp. 5399-5401
-
-
Ung, T.1
Hejl, A.2
Grubbs, R.H.3
Schrodi, Y.4
-
23
-
-
3342933323
-
-
(d) Slugovc, C.; Pemer, B.; Stelzer, F.; Mereiter, K. Organometallics 2004, 23, 3622-3626.
-
(2004)
Organometallics
, vol.23
, pp. 3622-3626
-
-
Slugovc, C.1
Pemer, B.2
Stelzer, F.3
Mereiter, K.4
-
24
-
-
42149097199
-
-
Ref 3a demonstrates that the metathesis activity of cis-catecholate catalysts can be very high, once initiation is effected.
-
(e) Ben-Asuly, A.; Tzur, E.; Diesendruck, C. E.; Sigalov, M.; Goldberg, I.; Lemcoff, N. G. Organometallics 2008, 27, 811-813. Ref 3a demonstrates that the metathesis activity of cis-catecholate catalysts can be very high, once initiation is effected.
-
(2008)
Organometallics
, vol.27
, pp. 811-813
-
-
Ben-Asuly, A.1
Tzur, E.2
Diesendruck, C.E.3
Sigalov, M.4
Goldberg, I.5
Lemcoff, N.G.6
-
26
-
-
0037010530
-
-
Fogg, D. E.; Amoroso, D.; Drouin, S. D.; Snelgrove, J.; Conrad, J.; Zamanian, F. J. Mol. Catal. A 2002, 190, 177-184.
-
(2002)
J. Mol. Catal. A
, vol.190
, pp. 177-184
-
-
Fogg, D.E.1
Amoroso, D.2
Drouin, S.D.3
Snelgrove, J.4
Conrad, J.5
Zamanian, F.6
-
27
-
-
0035800494
-
-
Fürstner, A.; Ackermann, L.; Gabor, B.; Goddard, R.; Lehmann, C. W.; Mynott, R.; Stelzer, F.; Thiel, O. R. Chem.-Eur. J. 2001, 7, 3236-3253.
-
(2001)
Chem.-Eur. J.
, vol.7
, pp. 3236-3253
-
-
Fürstner, A.1
Ackermann, L.2
Gabor, B.3
Goddard, R.4
Lehmann, C.W.5
Mynott, R.6
Stelzer, F.7
Thiel, O.R.8
-
28
-
-
33750328005
-
-
NHC bond on the NMR time scale at room temperature is not uncommon in aryl-NHC complexes. Selected examples: (a)
-
NHC bond on the NMR time scale at room temperature is not uncommon in aryl-NHC complexes. Selected examples: (a) Dible, B. R.; Sigman, M. S. Inorg. Chem. 2006, 45, 8430-8441.
-
(2006)
Inorg. Chem.
, vol.45
, pp. 8430-8441
-
-
Dible, B.R.1
Sigman, M.S.2
-
29
-
-
51049094204
-
-
(b) Ritleng, V; Barth, C.; Brenner, E.; Milosevic, S.; Chetcuti, M. J. Organometallics 2008, 27, 4223-4228.
-
(2008)
Organometallics
, vol.27
, pp. 4223-4228
-
-
Ritleng, V.1
Barth, C.2
Brenner, E.3
Milosevic, S.4
Chetcuti, M.J.5
-
30
-
-
64549141469
-
-
Ar rotation. See, for example
-
Ar rotation. See, for example:
-
(2009)
Organometallics
, vol.28
, pp. 1758-1775
-
-
Lee, J.P.1
Ke, Z.2
Ramirez, M.A.3
Gunnoe, T.B.4
Cundari, T.R.5
Boyle, P.D.6
Petersen, J.L.7
-
31
-
-
40849141961
-
-
(d) Gallagher, M. M.; Rooney, A. D.; Rooney, J. J. J. Organomet. Chem. 2008, 693, 1252-1260.
-
(2008)
J. Organomet. Chem.
, vol.693
, pp. 1252-1260
-
-
Gallagher, M.M.1
Rooney, A.D.2
Rooney, J.J.3
-
32
-
-
53849139133
-
-
For a recent exception, documented within a cis-anionic derivative, see ref 5e.
-
(e) Leuthaeusser, S.; Schmidts, V; Thiele, C. M.; Plenio, H. Chem.-Eur. J. 2008, 14, 5465-5481. For a recent exception, documented within a cis-anionic derivative, see ref 5e.
-
(2008)
Chem.-Eur. J.
, vol.14
, pp. 5465-5481
-
-
Leuthaeusser, S.1
Schmidts, V.2
Thiele, C.M.3
Plenio, H.4
-
33
-
-
0033620417
-
-
Selected examples include 2a and derivatives containing styrenyl ethers, esters, or sulfoxide. See: (a) Huang, J.; Stevens, E. D.; Nolan, S. P.;Petersen, J. L. J. Am. Chem. Soc. 1999, 121, 2674-2678.
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 2674-2678
-
-
Huang, J.1
Stevens, E.D.2
Nolan, S.P.3
Petersen, J.L.4
-
34
-
-
0034734340
-
-
(b)Garber, S. B.; Kingsbury, J. S.; Gray, B. L.; Hoveyda, A. H. J. Am. Chem. Soc. 2000, 122, 8168-8179.
-
(2000)
J. Am. Chem. Soc.
, vol.122
, pp. 8168-8179
-
-
Garber, S.B.1
Kingsbury, J.S.2
Gray, B.L.3
Hoveyda, A.H.4
-
35
-
-
0038002181
-
-
(c) Fürstner, A.; Thiel, O. R.; Lehmann, C. W. Organometallics 2002, 21, 331-335.
-
(2002)
Organometallics
, vol.21
, pp. 331-335
-
-
Fürstner, A.1
Thiel, O.R.2
Lehmann, C.W.3
-
36
-
-
66149133018
-
-
(d) Szadkowska, A.; Makal, A.; Wozniak, K.; Kadyrov, R.; Grela, K. Organometallics 2009, 28, 2693-2700.
-
(2009)
Organometallics
, vol.28
, pp. 2693-2700
-
-
Szadkowska, A.1
Makal, A.2
Wozniak, K.3
Kadyrov, R.4
Grela, K.5
-
37
-
-
0035843056
-
-
Sanford, M. S.; Love, J. A.; Grubbs, R. H. Organometallics 2001, 20, 5314-5318.
-
(2001)
Organometallics
, vol.20
, pp. 5314-5318
-
-
Sanford, M.S.1
Love, J.A.2
Grubbs, R.H.3
-
38
-
-
70349333664
-
-
Cooling to 223 K did not effect complete decoalescence. Heating to 323 K resulted in some sharpening of the signals, but coalescence was incomplete, and decomposition was observed over the time scale of analysis.
-
Cooling to 223 K did not effect complete decoalescence. Heating to 323 K resulted in some sharpening of the signals, but coalescence was incomplete, and decomposition was observed over the time scale of analysis.
-
-
-
-
39
-
-
33644909310
-
-
Conrad, J. C.; Camm, K. D.; Fogg, D. E. Inorg. Chim. Acta 2006, 359, 1967-1973.
-
(2006)
Inorg. Chim. Acta
, vol.359
, pp. 1967-1973
-
-
Conrad, J.C.1
Camm, K.D.2
Fogg, D.E.3
-
40
-
-
70349322530
-
-
-1, respectively.
-
-1, respectively.
-
-
-
-
41
-
-
70349305242
-
-
For a valuable related discussion, see ref 9a.
-
For a valuable related discussion, see ref 9a.
-
-
-
-
42
-
-
0032476166
-
-
Weskamp, T.; Schattenmann, W. C.; Spiegier, M.; Herrmann, W. A. Angew. Chem., Int. Ed. 1998, 37, 2490-2493.
-
(1998)
Angew. Chem., Int. Ed.
, vol.37
, pp. 2490-2493
-
-
Weskamp, T.1
Schattenmann, W.C.2
Spiegier, M.3
Herrmann, W.A.4
-
43
-
-
0038682047
-
-
Chianese, A. R.; Li, X.; Janzen, M. C.; Faller, J. W.; Crabtree, R. H. Organometallics 2003, 22, 1663-1667.
-
(2003)
Organometallics
, vol.22
, pp. 1663-1667
-
-
Chianese, A.R.1
Li, X.2
Janzen, M.C.3
Faller, J.W.4
Crabtree, R.H.5
-
46
-
-
61849180972
-
NMR spectroscopy and homogeneous catalysis
-
Heaton, B., Ed.; Wiley-VCH: Weinheim
-
Viviente, E. M.; Pregosin, P. S.; Schott, D. NMR spectroscopy and homogeneous catalysis. In Mechanisms in Homogeneous Catalysis; Heaton, B., Ed.; Wiley-VCH: Weinheim, 2005; pp 1-80.
-
(2005)
Mechanisms in Homogeneous Catalysis
, pp. 1-80
-
-
Viviente, E.M.1
Pregosin, P.S.2
Schott, D.3
-
47
-
-
84902424351
-
Nuclear magnetic resonance spectroscopy
-
Lever, A. B. P., Ed.; Elsevier: Oxford
-
Pregosin, P. S.; Rueegger, H., Nuclear magnetic resonance spectroscopy. In Comprehensive Coordination Chemistry II; Lever, A. B. P., Ed.; Elsevier: Oxford, 2004; Vol.2, pp 1-35.
-
(2004)
Comprehensive Coordination Chemistry II
, vol.2
, pp. 1-35
-
-
Pregosin, P.S.1
Rueegger, H.2
-
49
-
-
70349311383
-
-
0 groups on opposite rings. A distance of 2.83 Å is calculated for the DFT-optimized structure of 5, this value dropping to 2.27 À if rotation is permitted. In the crystal structure of 3b, the Me0 groups on opposite mesityl rings are as little as 2.75 A apart, well within the
-
0 groups on opposite rings. A distance of 2.83 Å is calculated for the DFT-optimized structure of 5, this value dropping to 2.27 À if rotation is permitted. In the crystal structure of 3b, the Me0 groups on opposite mesityl rings are as little as 2.75 A apart, well within the 4-5 À internuclear distance for direct NOE correlations. (Distances based on analysis of the crystallographic data for 3b, obtained from the Cambridge Crystallographic Data Centre (CCDC143577) at www.ccdc.cam.ac.uk/data- request/cif).
-
-
-
-
50
-
-
70349319496
-
-
13C HOESY Correlations between the Mesityl or Pyridine Protons and the Carbons of the Pentabromoaryloxide Ring Could in Principle Provide Positive Confirmation of the Trans-anionic Structure. These Experiments Are Hampered, However, by the Very Poor Signal-tonoise Ratios Characteristic of These Quaternary Carbons, Each of Which Bears A Quadrupolar Nuclide. the Relative Weakness of the NOE Enhancement (Ca. 2% of the Original Signal) Is Insufficient to Compensate for These Effects.
-
13C HOESY correlations between the mesityl or pyridine protons and the carbons of the pentabromoaryloxide ring could in principle provide positive confirmation of the trans-anionic structure. These experiments are hampered, however, by the very poor signal-tonoise ratios characteristic of these quaternary carbons, each of which bears a quadrupolar nuclide. The relative weakness of the NOE enhancement (ca. 2% of the original signal) is insufficient to compensate for these effects.
-
-
-
-
53
-
-
0345491105
-
-
Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785-789.
-
(1988)
Phys. Rev. B
, vol.37
, pp. 785-789
-
-
Lee, C.1
Yang, W.2
Parr, R.G.3
-
54
-
-
0001470765
-
-
Godbout, N.; Salahub, D. R.; Andzelm, J.; Wimmer, E. Can. J. Chem. 1992, 70, 560-571.
-
(1992)
Can. J. Chem.
, vol.70
, pp. 560-571
-
-
Godbout, N.1
Salahub, D.R.2
Andzelm, J.3
Wimmer, E.4
-
55
-
-
33846821470
-
-
Colacino, E.; Martinez, J.; Lamaty, F. Coord. Chem. Rev. 2007, 251, 726-764.
-
(2007)
Coord. Chem. Rev.
, vol.251
, pp. 726-764
-
-
Colacino, E.1
Martinez, J.2
Lamaty, F.3
-
56
-
-
46349105806
-
-
Burtscher, D.; Lexer, C.; Mereiter, K.; Winde, R.; Karch, R.; Slugovc, C. J. Polym. Sci., Part A 2008, 46, 4630-4635.
-
(2008)
J. Polym. Sci., Part A
, vol.46
, pp. 4630-4635
-
-
Burtscher, D.1
Lexer, C.2
Mereiter, K.3
Winde, R.4
Karch, R.5
Slugovc, C.6
-
57
-
-
0034660998
-
-
Sinha, P. K.; Falvello, L. R.; Peng, S. M.; Bhattacharya, S. Polyhedron 2000, 19, 1673-1680.
-
(2000)
Polyhedron
, vol.19
, pp. 1673-1680
-
-
Sinha, P.K.1
Falvello, L.R.2
Peng, S.M.3
Bhattacharya, S.4
-
58
-
-
0011522011
-
-
Darensbourg, D. J.; Fontal, B.; Chojnacki, S. S.; Klausmeyer, K. K.; Reibenspies, J. H. Inorg. Chem. 1994, 33, 3526-3532
-
(1994)
Inorg. Chem.
, vol.33
, pp. 3526-3532
-
-
Darensbourg, D.J.1
Fontal, B.2
Chojnacki, S.S.3
Klausmeyer, K.K.4
Reibenspies, J.H.5
-
59
-
-
0031571493
-
-
Werner, H.; Braun, T.; Daniel, T.; Gevert, O.; Schulz, M. J. Organomet. Chem. 1997, 541, 127-141.
-
(1997)
J. Organomet. Chem.
, vol.541
, pp. 127-141
-
-
Werner, H.1
Braun, T.2
Daniel, T.3
Gevert, O.4
Schulz, M.5
-
60
-
-
0033669431
-
-
Fries, G.; Hg, K.; Pfeiffer, M.; Stalke, D.; Werner, H. Eur. J. Inorg. Chem. 2000, 2597-2601.
-
(2000)
Eur. J. Inorg. Chem.
, pp. 2597-2601
-
-
Fries, G.1
Hg, K.2
Pfeiffer, M.3
Stalke, D.4
Werner, H.5
-
61
-
-
37049069753
-
-
Catala, R. M.; Cruz-Garritz, D.; Hills, A.; Hughes, D. L.; Richards, R. L.; Sosa, P.; Torrens, H. J. Chem. Soc., Chem. Commun. 1987, 261-262.
-
(1987)
J. Chem. Soc., Chem. Commun.
, pp. 261-262
-
-
Catala, R.M.1
Cruz-Garritz, D.2
Hills, A.3
Hughes, D.L.4
Richards, R.L.5
Sosa, P.6
Torrens, H.7
-
62
-
-
15744375697
-
-
Gaussian, Inc.: Wallingford, CT
-
Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A., Jr.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.;Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussian 03, Revision C.02; Gaussian, Inc.: Wallingford, CT, 2003.
-
(2003)
Gaussian 03, Revision C.02
-
-
Frisch, M.J.1
Trucks, G.W.2
Schlegel, H.B.3
Scuseria, G.E.4
Robb, M.A.5
Cheeseman, J.R.6
Montgomery Jr., J.A.7
Vreven, T.8
Kudin, K.N.9
Burant, J.C.10
Millam, J.M.11
Iyengar, S.S.12
Tomasi, J.13
Barone, V.14
Mennucci, B.15
Cossi, M.16
Scalmani, G.17
Rega, N.18
Petersson, G.A.19
Nakatsuji, H.20
Hada, M.21
Ehara, M.22
Toyota, K.23
Fukuda, R.24
Hasegawa, J.25
Ishida, M.26
Nakajima, T.27
Honda, Y.28
Kitao, O.29
Nakai, H.30
Klene, M.31
Li, X.32
Knox, J.E.33
Hratchian, H.P.34
Cross, J.B.35
Bakken, V.36
Adamo, C.37
Jaramillo, J.38
Gomperts, R.39
Stratmann, R.E.40
Yazyev, O.41
Austin, A.J.42
Cammi, R.43
Pomelli, C.44
Ochterski, J.W.45
Ayala, P.Y.46
Morokuma, K.47
Voth, G.A.48
Salvador, P.49
Dannenberg, J.J.50
Zakrzewski, V.G.51
Dapprich, S.52
Daniels, A.D.53
Strain, M.C.54
Farkas, O.55
Malick, D.K.56
Rabuck, A.D.57
Raghavachari, K.58
Foresman, J.B.59
Ortiz, J.V.60
Cui, Q.61
Baboul, A.G.62
Clifford, S.63
Cioslowski, J.64
Stefanov, B.B.65
Liu, G.66
Liashenko, A.67
Piskorz, P.68
Komaromi, I.69
Martin, R.L.70
Fox, D.J.71
Keith, T.72
Al-Laham, M.A.73
Peng, C.Y.74
Nanayakkara, A.75
Challacombe, M.76
Gill, P.M.W.77
Johnson, B.78
Chen, W.79
Wong, M.W.80
Gonzalez, C.81
Pople, J.A.82
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