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1
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64549160989
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For selected reviews on olefin metathesis, see: (a) Handbook of Metathesis; Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, Germany, 2003.
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For selected reviews on olefin metathesis, see: (a) Handbook of Metathesis; Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, Germany, 2003.
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7
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64549084402
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For detailed discussions, see: (a) Sanford, M. S.; Love, J. A. In ref la, 1. pp 112-131.
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For detailed discussions, see: (a) Sanford, M. S.; Love, J. A. In ref la, Vol. 1. pp 112-131.
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9
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0034814443
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(a) Sanford, M. S.; Love, J. A.; Grubbs, R. H. J. Am. Chem. Soc. 2001, 123, 6543-6554.
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J. Am. Chem. Soc
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Sanford, M.S.1
Love, J.A.2
Grubbs, R.H.3
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10
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3342982883
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(b) Michrowska, A.; Bujok, R.; Harutyunvan, S.; Sashuk, V.; Dolgonos, G.; Grela, K. J. Am. Chem. Soc. 2004, 126, 9318-9325.
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Michrowska, A.1
Bujok, R.2
Harutyunvan, S.3
Sashuk, V.4
Dolgonos, G.5
Grela, K.6
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11
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10144228427
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(c) Romero, P. E.; Piers, W. E.; McDonald, R. Angew. Chem., Int. Ed. 2004, 43, 6161-6165.
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Romero, P.E.1
Piers, W.E.2
McDonald, R.3
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13
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0030994105
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2) are ca. 19 (X = Cl). 15 (X = Br), and 1 (X = I). See: Dias. E. L.; Nguyen, S. T.; Grubbs. R. H. J. Am. Chem. Soc. 1997, 119, 3887-3897.
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2) are ca. 19 (X = Cl). 15 (X = Br), and 1 (X = I). See: Dias. E. L.; Nguyen, S. T.; Grubbs. R. H. J. Am. Chem. Soc. 1997, 119, 3887-3897.
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14
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0035796445
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Buchowicz, W.; Ingold. F.; Mol. J. C; Lutz. M.; Spek, A. L. Chem. Eur. J. 2001, 7, 2842-2847.
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Chem. Eur. J
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Buchowicz, W.1
Ingold, F.2
Mol, J.C.3
Lutz, M.4
Spek, A.L.5
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15
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20344392171
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Halbach, T. S.; Mrx, S.; Fischer, D.; Maechling, S.; Krause, J. O.; Sievers. C; Blechert, S.; Nuvken, O.; Buchmeiser, M. R. J. Org. Chem. 2005, 70, 4687-4694.
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Halbach, T.S.1
Mrx, S.2
Fischer, D.3
Maechling, S.4
Krause, J.O.5
Sievers, C.6
Blechert, S.7
Nuvken, O.8
Buchmeiser, M.R.9
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17
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33746410595
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2 isomers. See: (a) Barbasiewicz, M.; Szadkowska, A.; Bujok. R.; Grela, K. Organometallics 2006, 25, 3599-3604.
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2 isomers. See: (a) Barbasiewicz, M.; Szadkowska, A.; Bujok. R.; Grela, K. Organometallics 2006, 25, 3599-3604.
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18
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9144245653
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(b) Ung, T.; Hejl, A.; Grubbs, R. H.; Schrodi, Y. Organometallics 2004, 23, 5399-5401.
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Organometallics
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, pp. 5399-5401
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Ung, T.1
Hejl, A.2
Grubbs, R.H.3
Schrodi, Y.4
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20
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3342933323
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2 geometries may be associated with low activity. See: (a) Slugovc, C.; Perner, B.; Stelzer, F.; Mereiter, K. Organometallics 2004, 23, 3622-3626.
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2 geometries may be associated with low activity. See: (a) Slugovc, C.; Perner, B.; Stelzer, F.; Mereiter, K. Organometallics 2004, 23, 3622-3626.
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21
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42149097199
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(b) Ben-Asuly, A.; Tzur, E.; Diesendruck, C. E.; Sigalov, M.; Goldberg, I; Lemcoff, N. G. Organometallics 2008, 27, 811-813.
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Ben-Asuly, A.1
Tzur, E.2
Diesendruck, C.E.3
Sigalov, M.4
Goldberg, I.5
Lemcoff, N.G.6
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24
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33745685972
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Anderson, D. R.; Hickstein, D. D.; O'Leary, D. J.; Grubbs, R. H. J. Am. Chem. Soc. 2006, 128, 8386-8387.
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J. Am. Chem. Soc
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, pp. 8386-8387
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Anderson, D.R.1
Hickstein, D.D.2
O'Leary, D.J.3
Grubbs, R.H.4
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25
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64549122694
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For details, including numerical data where relevant, see the Supporting Information
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For details, including numerical data where relevant, see the Supporting Information.
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26
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0001050535
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Bohle, D. S.; Carron, K. T.; Christensen, A. N.; Goodson. P. A.; Powell, A. K. Organometallics 1994, 13, 1355-1373.
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Bohle, D.S.1
Carron, K.T.2
Christensen, A.N.3
Goodson, P.A.4
Powell, A.K.5
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38049032347
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Eelman, M. D.; Blacquiere, J. M.; Moriarty, M. M.; Fogg. D. E. Angew. Chem., Int. Ed. 2008, 47, 303-306.
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Eelman, M.D.1
Blacquiere, J.M.2
Moriarty, M.M.3
Fogg, D.E.4
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29
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0042020353
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31P NMR handle. For a useful analysis of deficiencies in prior kinetics studies of Ru catalysts with α,ω-olefins, particularly arising from co-formation of methylidene species, see: (a) Love, J. A.; Sanford, M. S.; Day, M. W.; Grubbs, R. H. J. Am. Chem. Soc. 2003, 125, 10103-10109.
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31P NMR handle. For a useful analysis of deficiencies in prior kinetics studies of Ru catalysts with α,ω-olefins, particularly arising from co-formation of methylidene species, see: (a) Love, J. A.; Sanford, M. S.; Day, M. W.; Grubbs, R. H. J. Am. Chem. Soc. 2003, 125, 10103-10109.
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30
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64549139188
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An alternative means of assaying Ki based on irreversible cross-metathesis with ethyl vinyl ether, requires high thermal stability where initiation efficiency is low (a condition not met by 6-8, For 1H NMR methods used to assess ki in ROMP, in which solely alkylidene species are formed, see: (b) Ivin, K. J, Mol, J. C, Olefin Metathesis and Metathesis Polymerization; Academic Press: New York, 1997; p 232
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i in ROMP, in which solely alkylidene species are formed, see: (b) Ivin, K. J.; Mol, J. C., Olefin Metathesis and Metathesis Polymerization; Academic Press: New York, 1997; p 232.
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31
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0029230067
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(c) Benedicto, A. D.; Claverie, J. P.; Grubbs, R. H. Macromolecules 1995, 28, 500-511.
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Macromolecules
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Benedicto, A.D.1
Claverie, J.P.2
Grubbs, R.H.3
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32
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0001684171
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(d) Bazan, G. C; Khosravi, E.; Schrock, R. R.; Feast. W. J.; Gibson, V. C; O'Regan, M. B.; Thomas, J. K.; Davrs, W. M. J. Am. Chem. Soc. 1990, 112, 8378-8387.
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Bazan, G.C.1
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Schrock, R.R.3
Feast, W.J.4
Gibson, V.C.5
O'Regan, M.B.6
Thomas, J.K.7
Davrs, W.M.8
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33
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0034296864
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Where NMR methods are not feasible, initiation efficiencies have been inferred from comparisons of ROMP polymer chain lengths with theoretical values. This requires that ring opening be irreversible and intramolecular chain transfer (backbiting) be slow. See, for example: (a) Six, C.; Beck, K.; Wegner, A.; Leitner, W. Organometallics 2000, 19, 4639-4642.
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Where NMR methods are not feasible, initiation efficiencies have been inferred from comparisons of ROMP polymer chain lengths with theoretical values. This requires that ring opening be irreversible and intramolecular chain transfer (backbiting) be slow. See, for example: (a) Six, C.; Beck, K.; Wegner, A.; Leitner, W. Organometallics 2000, 19, 4639-4642.
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34
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(b) Gstrein. X.; Burtscher, D.; Szadkowska, A.; Barbasiewicz, M.; Stelzer, F.; Grela, K.; Slugovc, C. J. Polym. Sci., Part A 2007, 45, 3494-3500.
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Burtscher, D.2
Szadkowska, A.3
Barbasiewicz, M.4
Stelzer, F.5
Grela, K.6
Slugovc, C.7
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(c) Nomura, K.; Sakai, L; lmanishi, Y.; Fujiki, M.; Miyamoto, Y. Macromol. Rapid Commun. 2004, 25, 571-576.
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Nomura, K.1
Sakai, L.2
lmanishi, Y.3
Fujiki, M.4
Miyamoto, Y.5
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36
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0027871953
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Backbiting of substituted polynorbornenes, inhibited by steric encumbrance and the high rigidity of the polymer chain, cannot normally compete with ROMP itself. See: d
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Backbiting of substituted polynorbornenes, inhibited by steric encumbrance and the high rigidity of the polymer chain, cannot normally compete with ROMP itself. See: (d) Breslow, D. S. Prog. Polym. Sci. 1993, 18, 1141-1195.
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(1993)
Prog. Polym. Sci
, vol.18
, pp. 1141-1195
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Breslow, D.S.1
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37
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64549088808
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The low initiation efficiencies of these catecholate catalysts may reflect the cis disposition of the anionic ligands: see ref 9
-
The low initiation efficiencies of these catecholate catalysts may reflect the cis disposition of the anionic ligands: see ref 9.
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38
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33751435606
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Wada, T.; Yamanaka, M.; Fujihara, T.; Miyazato. Y.; Tanaka, K. Inorg. Chem. 2006, 45, 8887-8894.
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Wada, T.1
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Tanaka, K.5
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