Gold-catalyzed intramolecular allylic amination of 2-tosylaminophenylprop- 1-en-3-ols. A concise synthesis of (±)-angustureine

Journal of Organic Chemistry

Volumn 74, Issue 16, 2009, Pages 5947-5952

  Kothandaraman, Prasath ^a   Shi, Jia Foo ^a   Chan, Philip Wai Hong ^a  

^a Nanyang Technological University   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; AMINATION; AMINES; CATALYSIS; CATALYSTS; ORGANIC POLYMERS; SILVER; SUBSTRATES; SULFUR COMPOUNDS; SYNTHESIS (CHEMICAL);

ALLYLIC AMINATION; CHEMICAL EQUATIONS; CONCISE SYNTHESIS; DIHYDROQUINOLINE; ELECTRON-DONATING; ELECTRONWITHDRAWING; ELECTROPHILES; GOLD AND SILVER; N-HETEROCYCLIC; NUCLEOPHILIC ADDITIONS; ROOM TEMPERATURE; STARTING MATERIALS; STERICALLY DEMANDING; SYNTHETIC ROUTES; TETRAHYDROQUINOLINE;

COMPLEXATION;

2 (PENT 1 ENYL) 1 TOSYL 1,2 DIHYDROQUINOLINE; 2 TOSYLAMINOPHENYLPROP 1 EN 3 OL; 4 METHYL 1 TOSYL 1,2 DIHYDROQUINOLINE; ALCOHOL; ALLYL COMPOUND; BENZENE DERIVATIVE; CATION; GOLD; NUCLEOPHILE; QUINOLINE DERIVATIVE; SILVER; SULFONAMIDE; UNCLASSIFIED DRUG; 1,4-DIHYDROQUINONE; ALKALOID; ALKENE; ANGUSTUREINE; PROPANOL; QUINONE DERIVATIVE;

AMINATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; ELECTRON; ELECTRON TRANSPORT; IONIZATION; ROOM TEMPERATURE; SYNTHESIS; CHEMISTRY; STEREOISOMERISM; TEMPERATURE;

1-PROPANOL; ALKALOIDS; ALKENES; AMINATION; CATALYSIS; GOLD; QUINOLINES; QUINONES; SILVER; STEREOISOMERISM; TEMPERATURE;

EID: 70349119910     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo900917q     Document Type: Article

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