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Typical Procedure for AuCl3-Catalyzed Direct Amination of Allylic Alcohols A solution of AuCl3 in MeCN (0.05 M) was prepared. Under N2 atmosphere, 1,3-diphenylprop-2-en-1-ol (1a, 0.11 g, 0.5 mmol) and p-ClC6H4NH2 (0.13 g, 1 mmol) were added to a 25 mL round-bottomed flask containing a stirring bar, and then 5 mL MeCN was added. To the mixture, 0.2 mL AuCl3 (0.01 mmol) was added. The resulting solution was stirred at 50°C until the reaction was completed as monitored by thin-layer chromatography (3 h, The solvent was removed in vacuo and the residue was purified by flash chromatography on silica gel (PE-EtOAc, 30:1) afforded product 2c in 92% isolated yield. N-(E, 4-Chlorophenyl, 1,3-diphenylallyl)amine (2c, 1H NMR (CDCl3, TMS, δ, 4.12 (br s, 1 H, 5.02 (d, J, 5.7 Hz, 1 H, 6.35 dd, J, 6.0, 15.9 Hz, 1 H, 6
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18ClN: 319.1128; found: 319.1121.
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