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Reaction of diethyl 4-fluorobenzylidene malonate with methyl ethyl ketone in the presence of catalyst 6c and TFA in NMP at 28 °C gave a ∼3:. See the Supporting Information for details
-
Reaction of diethyl 4-fluorobenzylidene malonate with methyl ethyl ketone in the presence of catalyst 6c and TFA in NMP at 28 °C gave a ∼3:2 mixture of regioisomers with Me end addition product as the major. See the Supporting Information for details.
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2 mixture of regioisomers with Me end addition product as the major
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Enantiomeric excess of 8 was found to be 90% by HPLC analysis.
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Enantiomeric excess of 8 was found to be 90% by HPLC analysis.
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Hydrolysis of β-silyl esters do not epimerize the β-C center. See ref 3
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