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Meyer, C.D.1
Joiner, C.S.2
Stoddart, J.F.3
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96
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67849118584
-
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The reported ionic radii were obtained from the Handbook of Chemistry and Physics, 82th ed.
-
The reported ionic radii were obtained from the Handbook of Chemistry and Physics, 82th ed.
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97
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0035805266
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Nguyen, R.; Huc, I. Angew. Chem., Int. Ed. 2001, 40, 1774-1776.
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98
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67849128517
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2.
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2.
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99
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67849092239
-
-
The presence of the central hydrazone unit makes the whole molecule dissymmetric. Therefore the two hemi-aminals do not have the same reactivity. The one on the pyridine aldehyde side is expected to be more stable than that on the pyridine hydrazine side
-
The presence of the central hydrazone unit makes the whole molecule dissymmetric. Therefore the two hemi-aminals do not have the same reactivity. The one on the pyridine aldehyde side is expected to be more stable than that on the pyridine hydrazine side.
-
-
-
-
100
-
-
67849115956
-
-
2O upon addition of DMAP, imidazole, or pyridine (see Supporting Information).
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2O upon addition of DMAP, imidazole, or pyridine (see Supporting Information).
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101
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0034826979
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Piotrowski, H.; Polborn, K.; Hilt, G.; Severin, K. J. Am. Chem. Soc. 2001, 123, 2699-2700.
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Piotrowski, H.1
Polborn, K.2
Hilt, G.3
Severin, K.4
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103
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67849124135
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-
After addition of lead triflate, imine hydrolysis was observed. This can be explained by the fact that additional imines can coordinate the metallo-macrocycle in its axial position (see text) and therefore activate the imine towards a nucleophilic attack from residual water. Imidazole can prohibit that by occupying the axial position of the metallo-macrocycle as it has been previously proven see text, It also makes the medium more basic which helps the formation of imines
-
After addition of lead triflate, imine hydrolysis was observed. This can be explained by the fact that additional imines can coordinate the metallo-macrocycle in its axial position (see text) and therefore activate the imine towards a nucleophilic attack from residual water. Imidazole can prohibit that by occupying the axial position of the metallo-macrocycle as it has been previously proven (see text). It also makes the medium more basic which helps the formation of imines.
-
-
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104
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30444457020
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For systems chemistry, see for instance:a
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For systems chemistry, see for instance:(a) Stankiewicz, J.; Eckhardt, L. H. Angew. Chem. In.Ed. 2006, 45, 342-344.
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Stankiewicz, J.1
Eckhardt, L.H.2
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84889582115
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Gottlieb, H. E.; Kotlyar, V.; Nudelman, A. J. Org. Chem. 1997, 62, 7512-7515.
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Gottlieb, H.E.1
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