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see ref. [14d] for the nickel-catalysed conversion of 4 to 5
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c) see ref. [14d] for the nickel-catalysed conversion of 4 to 5.
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65
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0001392815
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For another type of quadruply stranded helicate, see; D. A. McMorran, P. J. Steel, Angew. Chem. 1998, 110, 3495; Angew. Chem. Int. Ed. 1998, 37, 3295.
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I bond lengths (2.8-2.9 A) are relatively rare but have been described, see for example: a) M. Munakata, M. Maekawa, S. Kitagawa, M. Adachi, H. Masuda, Inorg. Chim. Acta, 1990, 167, 181;
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G. V. Long, S. E. Boyd, M. M. Harding, I. E. Buys, T. W. Hambley, J. Chem. Soc. Dalton Trans. 1993, 3175.
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