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For examples of pH controllable metal ion-mediated self-assembly, see: a) N. Matsumoto, Y. Mizuguchi, G. Mago, S. Eguchi, H. Miyasaka, T. Nakashima, J.-P. Tuchagues, Angew. Chem. 1997, 109, 1964; Angew. Chem. Int. Ed. Engl. 1997, 36, 1860; P. Jacopozzi, E. Dalcanale, Angew. Chem. 1997, 109, 665; Angew. Chem. Int. Ed. Engl. 1997, 36, 613.
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60
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0001002954
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b) For electrochemically switchable systems, see for instance: J.-P. Gisselbrecht, M. Gross, J.-M. Lehn, J.-P. Sauvage, R. Ziessel, C. Piccini-Leopardi, J. M. Arrieta, G. Germain, M. Van Meersche, Nouv. J. Chim. 1984, 8, 661, and Figure 3, J.-M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, VCH, Weinheim, 1995, p. 132; see also ret. 8a and references therein.
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Gisselbrecht, J.-P.1
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Van Meersche, M.9
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61
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VCH, Weinheim, see also ret. 8a and references therein
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b) For electrochemically switchable systems, see for instance: J.-P. Gisselbrecht, M. Gross, J.-M. Lehn, J.-P. Sauvage, R. Ziessel, C. Piccini-Leopardi, J. M. Arrieta, G. Germain, M. Van Meersche, Nouv. J. Chim. 1984, 8, 661, and Figure 3, J.-M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, VCH, Weinheim, 1995, p. 132; see also ret. 8a and references therein.
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Lehn, J.-M.1
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64
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85037457699
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note
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12.
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65
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84970591771
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See for example: a) J. R. Hall, M. R. Litzow, R. A. Plowman, Aust. J. Chem. 1965, 18, 1331;
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Hall, J.R.1
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66
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and references therein
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b) K. T. Potts, M. Keshavarz-K, F. S. Than, H. D. Abruña, C. R. Arana, Inorg. Chem. 1993, 32, 4422, and references therein;
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c) C. O. Dietrich-Buchecker, J.-P. Sauvage, J.-M. Kern, J. Am. Chem. Soc. 1989, 111, 7791;
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Dietrich-Buchecker, C.O.1
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d) A. Livoreil, C. O. Dietrich-Buchecker, J.-P. Sauvage, J. Am. Chem. Soc. 1994, 116, 9399.
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B. Hasenknopf, J.-M. Lehn, G. Baum, D. Fenske, Proc. Natl. Acad. Sci. USA 1996, 93, 1397.
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D. J. Cárdenas, A. Livoreil, J.-P. Sauvage, J. Am. Chem. Soc. 1996, 118, 11 980.
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71
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85037489465
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note
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2, a fifth coordination site is sterically accessible to small molecules and may be occupied by either solvent or counterions, as observed in the crystal structure of 2.
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72
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R. Krämer, J. M.-Lehn, A. Marquis-Rigault, Proc. Natl. Acad. Sci. USA 1993, 90, 5394.
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G. S. Hanan, U. S. Schubert, D. Volkmer, E. Rivière, J.-M. Lehn, N. Kyritsakas, J. Fischer, Can. J. Chem. 1997, 75, 169.
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Hanan, G.S.1
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Kyritsakas, N.6
Fischer, J.7
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74
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85037482545
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note
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A detailed ES mass spectrometric speciation analysis of this and related systems will be published elsewhere, P. N. W. Baxter, J.-M. Lehn, H. Nierengarten, E. Leize, A. Van Dorsselaer.
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75
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a) M. Fujita, S. Nagao, K. Ogura, J. Am. Chem. Soc. 1995, 117, 1949; S. B. Lee, S. Hwang, D. S. Chung, H. Yun, J.-I. Hong, Tetrahedron Lett. 1998, 39, 873; M. Albrecht, O. Blau, R. Frölich, Chem. Eur. J. 1999, 5, 48;
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a) M. Fujita, S. Nagao, K. Ogura, J. Am. Chem. Soc. 1995, 117, 1949; S. B. Lee, S. Hwang, D. S. Chung, H. Yun, J.-I. Hong, Tetrahedron Lett. 1998, 39, 873; M. Albrecht, O. Blau, R. Frölich, Chem. Eur. J. 1999, 5, 48;
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Lee, S.B.1
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a) M. Fujita, S. Nagao, K. Ogura, J. Am. Chem. Soc. 1995, 117, 1949; S. B. Lee, S. Hwang, D. S. Chung, H. Yun, J.-I. Hong, Tetrahedron Lett. 1998, 39, 873; M. Albrecht, O. Blau, R. Frölich, Chem. Eur. J. 1999, 5, 48;
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Albrecht, M.1
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b) For substrate inclusion in a hydrogen-bonded capsule, see for instance: J. Rebek, Acc. Chem. Res. 1999, 32, 278; A. Lützen, A. R. Renslo, C. A. Schalley, B. M. O'Leavy, J. Rebek, J. Am. Chem. Soc. 1999, 121, 7455;
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79
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0344993966
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b) For substrate inclusion in a hydrogen-bonded capsule, see for instance: J. Rebek, Acc. Chem. Res. 1999, 32, 278; A. Lützen, A. R. Renslo, C. A. Schalley, B. M. O'Leavy, J. Rebek, J. Am. Chem. Soc. 1999, 121, 7455;
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Lützen, A.1
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Rebek, J.5
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80
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0031877894
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c) For templation by solvent, see: Y. Tokunaga, D. M. Rudkevich, J. Santamaría, G. Hilmersson, J. Rebek, Chem. Eur. J. 1998, 4, 1449.
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81
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85037455286
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note
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It is not known how many species are included. This depends on their ability to fit into the cavity taking into account their size, the cavity size, and eventual bending to release steric strain.
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82
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0030898702
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I. Huc, J.-M. Lehn, Proc. Natl. Acad. Sci. USA 1997, 94, 2106; I. Huc, J.-M. Lehn, Proc. Natl. Acad. Sci. USA 1997, 94, 8272.
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Huc, I.1
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I. Huc, J.-M. Lehn, Proc. Natl. Acad. Sci. USA 1997, 94, 2106; I. Huc, J.-M. Lehn, Proc. Natl. Acad. Sci. USA 1997, 94, 8272.
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