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1H NMR is that it is unable to detect minor species (< 3%). This limitation is probably larger in this study since crossover aggregates are likely to be less symmetrical than the self-sorted species.
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1H NMR spectra of the individual components from that of the mixture. Unfortunately, spectral broadening in the mixture which can be due to either dynamic exchange processes within the homomeric aggregates of crossover heteromeric aggregates, makes spectral subtraction uninformative. We also performed EXSY and selective ID ROESY experiments. but did not observe signals that could be assigned to crossover aggregates.
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39
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0242617567
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note
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A under the constraints employed.
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