Versatile coordination of 2-pyridinetetramethyldisilazane at ruthenium: Ru(II) vs Ru(IV) as evidenced by NMR, X-ray, neutron, and DFT studies

Journal of the American Chemical Society

Volumn 131, Issue 22, 2009, Pages 7633-7640

  Grellier, Mary ^a,b   Ayed, Tahra ^c   Barthelat, Jean Claude ^c   Albinati, Alberto ^d   Mason, Sax ^e   Vendier, Laure ^a,b   Coppel, Yannick ^a,b   Sabo Etienne, Sylviane ^a,b  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b UNIVERSITÉ DE TOULOUSE   (France)

^c European Theoretical Spectroscopy Facility   (France)

^d UNIVERSITY OF MILAN   (Italy)

^e INSTITUT LAUE LANGEVIN   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DEHYDROGENATION REACTIONS; DFT CALCULATION; DFT STUDY; DIHYDROGEN; DISILAZANE; ELECTRON COMPLEXES; FUNCTIONALIZATION; HYDROGEN ATOMS; MULTINUCLEAR NMR; NEUTRON PARAMETERS; RUTHENIUM COMPLEXES; SI-H BONDS; SILICON ATOMS; VAN DER WAALS RADIUS; X-RAY AND NEUTRON DIFFRACTION;

ATOMS; COORDINATION REACTIONS; DEHYDROGENATION; DEUTERIUM; DIFFRACTION; EXPERIMENTS; HYDROGEN; LABELS; NEUTRONS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROBABILITY DENSITY FUNCTION; RUTHENIUM; RUTHENIUM COMPOUNDS; SILANES; STABILIZATION; SULFUR COMPOUNDS; VAN DER WAALS FORCES;

SILICON;

2 PYRIDINETETRAMETHYLDISILAZANE; DEUTERIUM; HYDROGEN; POLYMER; RUTHENIUM COMPLEX; SILICON; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CHEMICAL BINDING; CHEMICAL LABELING; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; DEHYDROGENATION; ELECTRON; FOURIER TRANSFORMATION; HEATING; HETERONUCLEAR MULTIPLE BOND CORRELATION; ISOMER; MOLECULAR INTERACTION; NEUTRON DIFFRACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS; VACUUM; X RAY DIFFRACTION;

EID: 67650517067     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja901140v     Document Type: Article

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