Agostic interaction and intramolecular proton transfer from the protonation of dihydrogen ortho metalated ruthenium complexes

Proceedings of the National Academy of Sciences of the United States of America

Volumn 104, Issue 17, 2007, Pages 6945-6950

  Toner, Andrew ^a   Matthes, Jochen ^a,b   Gründemann, Stephan ^b   Limbach, Hans Heinrich ^b   Chaudret, Bruno ^a   Clot, Eric ^c   Sabo Etienne, Sylviane ^a  

^a CNRS   (France)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

^c UNIVERSITÉ DE MONTPELLIER   (France)

Author keywords

C H activation; Density functional theory; Hydrogen transfer; NMR; Sigma bonds

Indexed keywords

CARBONYL DERIVATIVE; HYDROGEN; PYRIDINE DERIVATIVE; QUINOLINE DERIVATIVE; RUTHENIUM COMPLEX;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; DENSITY FUNCTIONAL THEORY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRIORITY JOURNAL; PROTON TRANSPORT; TEMPERATURE DEPENDENCE; X RAY DIFFRACTION;

EID: 34547518259     PISSN: 00278424     EISSN: None     Source Type: Journal    
DOI: 10.1073/pnas.0608979104     Document Type: Article

References (46)

1. Sen A (1998) Acc Chem Res 31:550-557.
2. Guari Y, Sabo-Etienne S, Chaudret B (1999) Eur J Inorg Chem 7:1047-1055.
3. Kakiuchi F, Murai S (1999) Topics in Organometallic Chem 3:47-79.
4. Dyker G (1999) Angew Chem Int Ed 38:1699-1712.
5. Jia C, Kitamura T, Fujiwara Y (2001) Acc Chem Res 34:633-639.
6. Trost BM, Toste FD, Pinkerton AB (2001) Chem Rev 101:2067-2096.
7. Ritleng V, Sirlin C, Pfeffer M (2002) Chem Rev 102:1731-1769.
8. Kakiuchi F, Murai S (2002) Acc Chem Res 35:826-834.
9. Kakiuchi F, Chatani N (2003) Adv Synth Catal 345:1077-1101.
10. Kubas GJ (2005) Catal Leu 104:79-101.
11. Ishiyama T, Miyaura N (2003) J Organomet Chem 680:3-11.
12. Goldman AS, Goldberg KI (2004) ACS Symp Ser 885:1-43.
13. Hartwig JF, Cook KS, Hapke M, Incarvito CD, Fan Y, Webster CE, Hall MB (2005) J Am Chem Soc 127:2538-2552.
14. Crabtree RH (1985) Chem Rev 85:245-269.
15. Jones WD, Feher FJ (1989) Acc Chem Res 22:91-100.
16. Arndtsen BA, Bergman RG, Mobley TA, Peterson TH (1995) Acc Chem Res 28:154-162.
17. Shilov AE, Shul'pin GB (1997) Chem Rev 97:2879-2932.
18. Stahl SS, Labinger JA, Bercaw JE (1998) Angew Chem Int Ed 37:2181-2192.
19. Jones WD (1999) Topics Organometallic Chem 3:9-46.
20. Crabtree RH (2001) J Chem Soc Dalton Trans 24372450. 2437-2450.
21. Labinger JA, Bercaw JE (2002) Nature 417:507-514.
22. Jones WD (2005) Inorg Chem 44:4475-4484.
23. Crabtree RH (2004) J Organomet Chem 689:4083-4091.
24. Lersch M, Tilset M (2005) Chem Rev 105:2471-2526.
25. Owen JS, Labinger JA, Bercaw JE (2006) J Am Chem Soc 128:2005-2016.
26. Feller M, Karton A, Leitus G, Martin JML, Milstein D (2006) J Am Chem Soc 128:12400-12401.
27. Perutz RN, Sabo-Etienne S (2007) Angew Chem Int Ed, in press.
28. Hall C, Perutz RN (1996) Chem Rev 96:3125-3146.
29. Lawes DJ, Geftakis S, Ball GE (2005) J Am Chem Soc 127:4134-4135.
30. Murai S, Kakiuchi F, Sekine S, Tanaka Y, Kamatani A, Sonoda M, Chatani N (1993) Nature 366:529-531.
31. Guari Y, Sabo-Etienne S, Chaudret B (1998) J Am Chem Soc 120:4228-4229.
32. Guari Y, Castellanos A, Sabo-Etienne S, Chaudret B (2004) J Mol Cata A 212:77-82.
33. Grellier, M. Vendier L, Chaudret B, Albinati A, Rizzato S, Mason SA, Sabo-Etienne S (2005) J Am Chem Soc 127:17592-17593.
34. Matthes J, Gründemann S, Toner A, Guari Y, Donnadieu B, Spandl J, Sabo-Etienne S, Clot E, Limbach H-H, Chaudret B (2004) Organometallics 23:1424-1433.
35. Toner AJ, Gründemann S, Clot E, Limbach H-H, Donnadieu B, Sabo-Etienne S, Chaudret B (2000) J Am Chem Soc 122:6777-6778.
36. Albeniz AC, Schulte G, Crabtree RH (1992) Organometallics 11:242-249.
37. Brookhart M, Green MLH, Wong LL (1988) Prog Inorg Chem 36:1-124.
38. Kubas GJ (2001) Metal Dihydrogen and s-Bond Complexes (Kluwer Academic/Plenum, New York).
39. Sabo-Etienne S, Chaudret B (1998) Chem Rev 98:2077-2091.
40. Vigalok A, Uzan O, Shimon LJW, Ben-David Y, Martin JML, Milstein D (1998) J Am Chem Soc 120:12539-12544.
41. Rybtchinski B, Konstantinovsky L, Shimon LJW, Vigalok A, Milstein D (2000) Chem Eur J 6:3287-3292.
42. Rybtchinski B, Cohen R, Ben-David Y, Martin JML, Milstein D (2003) J Am Chem Soc 125:11041-11050.
43. Gonzalez AA, Zhang K, Nolan SP, Lopez de la Vega R, Mukerjee SL, Hoff CD, Kubas GJ (1988) Organometallics 7:2429-2435.
44. Reed AE, Curtiss LA, Weinhold F (1988) Chem Rev 88:899-926.
45. Oxgaard J, Periana RA, Goddard WA, III (2004) J Am Chem Soc 126:11658-11665.
46. Brookhart M, Grant B, Volpe AF, JR (1992) Organometallics 11:3920-3922.