X-ray structure and theoretical studies of RuH2(η2-H2)(η2-H-SiPh3) (PCy3)2, a complex with two different η2-coordinated σ bonds

Chemical Communications

Volumn , Issue 14, 1999, Pages 1315-1316

  Hussein, Khansaa ^a,c   Marsden, Colin J ^a   Barthelat, Jean Claude ^a   Rodriguez, Venancio ^b   Conejero, Salvador ^b   Sabo Etienne, Sylviane ^b   Donnadieu, Bruno ^b   Chaudret, Bruno ^b  

^a European Theoretical Spectroscopy Facility   (France)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^c University of Al Baath   (Syrian Arab Republic)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; RUTHENIUM COMPLEX; SILICON;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; THEORETICAL STUDY; X RAY ANALYSIS;

EID: 0033591874     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a901558b     Document Type: Article

References (24)

1. For reviews on dihydrogen complexes chemistry: G. J. Kubas, Acc. Chem. Res., 1988, 21, 120; R. H. Crabtree, Acc. Chem. Res., 1990, 23, 95 ; P. G. Jessop and R. H. Morris, Coord. Chem., Rev., 1992, 121, 155; D. M. Heinekey and W. J. Oldham Jr., Chem. Rev., 1993, 93, 913; R. H. Crabtree, Angew. Chem., Int. Ed. Engl., 1993, 32, 789; M. A. Esteruelas and L. A. Oro, Chem. Rev., 1998, 98, 577.
2. For reviews on dihydrogen complexes chemistry: G. J. Kubas, Acc. Chem. Res., 1988, 21, 120; R. H. Crabtree, Acc. Chem. Res., 1990, 23, 95 ; P. G. Jessop and R. H. Morris, Coord. Chem., Rev., 1992, 121, 155; D. M. Heinekey and W. J. Oldham Jr., Chem. Rev., 1993, 93, 913; R. H. Crabtree, Angew. Chem., Int. Ed. Engl., 1993, 32, 789; M. A. Esteruelas and L. A. Oro, Chem. Rev., 1998, 98, 577.
3. For reviews on dihydrogen complexes chemistry: G. J. Kubas, Acc. Chem. Res., 1988, 21, 120; R. H. Crabtree, Acc. Chem. Res., 1990, 23, 95 ; P. G. Jessop and R. H. Morris, Coord. Chem., Rev., 1992, 121, 155; D. M. Heinekey and W. J. Oldham Jr., Chem. Rev., 1993, 93, 913; R. H. Crabtree, Angew. Chem., Int. Ed. Engl., 1993, 32, 789; M. A. Esteruelas and L. A. Oro, Chem. Rev., 1998, 98, 577.
4. For reviews on dihydrogen complexes chemistry: G. J. Kubas, Acc. Chem. Res., 1988, 21, 120; R. H. Crabtree, Acc. Chem. Res., 1990, 23, 95 ; P. G. Jessop and R. H. Morris, Coord. Chem., Rev., 1992, 121, 155; D. M. Heinekey and W. J. Oldham Jr., Chem. Rev., 1993, 93, 913; R. H. Crabtree, Angew. Chem., Int. Ed. Engl., 1993, 32, 789; M. A. Esteruelas and L. A. Oro, Chem. Rev., 1998, 98, 577.
5. For reviews on dihydrogen complexes chemistry: G. J. Kubas, Acc. Chem. Res., 1988, 21, 120; R. H. Crabtree, Acc. Chem. Res., 1990, 23, 95 ; P. G. Jessop and R. H. Morris, Coord. Chem., Rev., 1992, 121, 155; D. M. Heinekey and W. J. Oldham Jr., Chem. Rev., 1993, 93, 913; R. H. Crabtree, Angew. Chem., Int. Ed. Engl., 1993, 32, 789; M. A. Esteruelas and L. A. Oro, Chem. Rev., 1998, 98, 577.
6. For reviews on dihydrogen complexes chemistry: G. J. Kubas, Acc. Chem. Res., 1988, 21, 120; R. H. Crabtree, Acc. Chem. Res., 1990, 23, 95 ; P. G. Jessop and R. H. Morris, Coord. Chem., Rev., 1992, 121, 155; D. M. Heinekey and W. J. Oldham Jr., Chem. Rev., 1993, 93, 913; R. H. Crabtree, Angew. Chem., Int. Ed. Engl., 1993, 32, 789; M. A. Esteruelas and L. A. Oro, Chem. Rev., 1998, 98, 577.
7. For reviews on silane complexes: (a) U. Schubert, Adv. Organomet. Chem., 1990, 30, 151;
8. (b) J. Y. Corey and J. Braddock-Wilking, Chem. Rev., 1999, 99, 175.
9. S. Sabo-Etienne and B. Chaudret, Coord. Chem. Rev., 1998, 178-180, 381.
10. M. L. Christ, S. Sabo-Etienne and B. Chaudret, Organometallics, 1995, 14, 1082; F. Delpech, S. Sabo-Etienne, B. Donnadieu and B. Chaudret, Organometallics, 1998, 17, 4926.
11. M. L. Christ, S. Sabo-Etienne and B. Chaudret, Organometallics, 1995, 14, 1082; F. Delpech, S. Sabo-Etienne, B. Donnadieu and B. Chaudret, Organometallics, 1998, 17, 4926.
12. (a) F. Delpech, S. Sabo-Etienne, B. Chaudret and J. C. Daran, J. Am. Chem. Soc., 1997, 119, 3167;
13. (b) F. Delpech, S. Sabo-Etienne, B. Chaudret, J. C. Daran, K. Hussein, C. J. Marsden and J.-C. Barthelat J. Am. Chem. Soc., 1999, in press.
14. S. Sabo-Etienne, M. Hernandez, G. Chung, B. Chaudret and A. Castel, New J. Chem., 1994, 18, 175.
15. V. Rodriguez, S. Sabo-Etienne, B. Chaudret, J. Thoburn, S. Ulrich, H.-H. Limbach, J. Eckert, J.-C. Barthelat, K. Hussein and C. J. Marsden, Inorg. Chem., 1998, 37, 3475.
16. Gaussian 94, M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. A. Keith, G. A. Petersson, J. A. Montgomery, K. Raghavachari, M. A. Al-Laham, V. G. Zakrewski, J. V. Ortiz, J. B. Foresman, J. Cioslowski, B. B. Stefanov, A. Nanayakkara, M. Challacombe, C. Y. Peng, P. Y. Ayala, W. Chen, M. W. Wong, J. L. Andres, E. S. Replogle, R. Gomperts, R. L. Martin, D. J. Fox, J. S. Binkley, D. J. Defrees, J. Baker, J. P. Stewart, M. Head-Gordon, C. Gonzalez and J. A. Pople, Gaussian, Inc., Pittsburgh PA, 1995.
17. Y. Bouteiller, C. Mijoule, M. Nizam, J.-C. Barthelat, J.-P. Daudey, M. Pélissier and B. Silvi. Mol. Phys., 1988, 65, 2664.
18. G. I. Nikonov, L. G. Kuzmina, D. A. Lemenovskii and V. V. Kotov, J. Am. Chem. Soc., 1995, 117, 10133; M.-F. Fan and Z. Lin, Organometallics, 1998, 17, 1092.
19. G. I. Nikonov, L. G. Kuzmina, D. A. Lemenovskii and V. V. Kotov, J. Am. Chem. Soc., 1995, 117, 10133; M.-F. Fan and Z. Lin, Organometallics, 1998, 17, 1092.
20. See, for example, R. H. Crabtree, P. E. M. Siegbahn, O. Eisenstein, A. L. Rheingold and T. F. Koetzle, Acc. Chem. Res., 1996, 29, 348; S. Park, A. J. Lough and R. H. Morris, Inorg. Chem., 1996, 35, 3001; J. A. Ayllon, S. Sabo-Etienne, B. Chaudret, S. Ulrich and H.-H. Limbach, Inorg. Chim. Acta, 1997, 259, 1; A. Castellanos, J. A. Ayllon, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, W. Yao, K. Kavallieratos and R. H. Crabtree, C. R. Acad. Sci. 1999, in press.
21. See, for example, R. H. Crabtree, P. E. M. Siegbahn, O. Eisenstein, A. L. Rheingold and T. F. Koetzle, Acc. Chem. Res., 1996, 29, 348; S. Park, A. J. Lough and R. H. Morris, Inorg. Chem., 1996, 35, 3001; J. A. Ayllon, S. Sabo-Etienne, B. Chaudret, S. Ulrich and H.-H. Limbach, Inorg. Chim. Acta, 1997, 259, 1; A. Castellanos, J. A. Ayllon, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, W. Yao, K. Kavallieratos and R. H. Crabtree, C. R. Acad. Sci. 1999, in press.
22. See, for example, R. H. Crabtree, P. E. M. Siegbahn, O. Eisenstein, A. L. Rheingold and T. F. Koetzle, Acc. Chem. Res., 1996, 29, 348; S. Park, A. J. Lough and R. H. Morris, Inorg. Chem., 1996, 35, 3001; J. A. Ayllon, S. Sabo-Etienne, B. Chaudret, S. Ulrich and H.-H. Limbach, Inorg. Chim. Acta, 1997, 259, 1; A. Castellanos, J. A. Ayllon, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, W. Yao, K. Kavallieratos and R. H. Crabtree, C. R. Acad. Sci. 1999, in press.
23. See, for example, R. H. Crabtree, P. E. M. Siegbahn, O. Eisenstein, A. L. Rheingold and T. F. Koetzle, Acc. Chem. Res., 1996, 29, 348; S. Park, A. J. Lough and R. H. Morris, Inorg. Chem., 1996, 35, 3001; J. A. Ayllon, S. Sabo-Etienne, B. Chaudret, S. Ulrich and H.-H. Limbach, Inorg. Chim. Acta, 1997, 259, 1; A. Castellanos, J. A. Ayllon, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, W. Yao, K. Kavallieratos and R. H. Crabtree, C. R. Acad. Sci. 1999, in press.
24. C. K. Johnson, ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.